TRIS(2-METHYLPHENYL)PHOSPHORANE, A MODIFIED SEYFERTH-WITTIG REAGENT FOR THE STEREOSELECTIVE SYNTHESES OF Z-ALLYLTRIMETHYLSILANES

DOI: 10.1016/S0040-4039(00)82241-8

Source and publish data:

Tetrahedron Letters p. 5965 - 5968 (1988)

Update date:2022-08-03

Topics:

Authors:

Iio, Hideo

Ishii, Masahiro

Tsukamoto, Masamitsu

Tokoroyama, Takashi

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Article abstract of DOI:10.1016/S0040-4039(00)82241-8

The Wittig reactions between title β-silylphosphorus ylide and aliphatic aldehydes give selectively Z-allyltrimethylsilanes with minimal formation of vinylation products.

Full text of DOI:10.1016/S0040-4039(00)82241-8

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Product name:trimethyl(4-phenyl-2-penten-1-yl)silane

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