Stereospecificity in the Lewis acid promoted allylation reaction of 3,3- disubstituted allyltins toward aldehydes

DOI: 10.1016/S0040-4039(98)80032-4

Source and publish data:

Tetrahedron Letters p. 109 - 112 (1999)

Update date:2022-08-10

Topics:

Authors:

Nishigaichi, Yutaka

Takuwa, Akio

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Article abstract of DOI:10.1016/S0040-4039(98)80032-4

The Lewis acid-promoted reaction of 3,3-disubstituted allyltins toward aldehydes was found to be stereospecific; the (E)-reagent gave syn-products and the (Z)-one gave anti-products. This is in contrast to that of 3-mono- substituted congeners which are k

Full text of DOI:10.1016/S0040-4039(98)80032-4

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