Silacyclobutene Synthesis via Intramolecular Cyclization of Unsaturated Silylenes

DOI: 10.1021/ja00345a056

Source and publish data:

Journal of the American Chemical Society p. 2006 - 2009 (1983)

Update date:2022-08-16

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Authors:

Burns, Gary T.

Barton, Thomas J.

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Article abstract of DOI:10.1021/ja00345a056

Flash vacuum pyrolysis of methoxydisilanes is used to generate 1-, 2-, and 3-propenylsilylenes.Each of these silylenes affords siletene (silacyclobutene) products although the mechanistic origins are probably different in each case.Isobutenylmethylsilylen

Full text of DOI:10.1021/ja00345a056

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