Bulletin of the Chemical Society of Japan p. 870 - 876 (1993)
Update date:2022-08-17
Topics:
Hatsui, Toshihide
Ikeda, Shin-ya
Takeshita, Hitoshi
A series of proto-photocycloadducts of methyl 2,4-dioxopentanoate to methylenecycloalkanes and -alkenes spontaneously caused retro-benzilic acid rearrangement in high yields.The results are utterly different from those of sterically-crowded acyclic alkenes, with which the rearrangement occurred by thermolysis as a minor process.
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