Synlett p. 1239 - 1240 (1997)
Update date:2022-08-18
Topics:
Szymoniak, Jan
Thery, Nadine
Mo?se, Claude
η3-2-Methylcrotyl(tiglyl)titanocene reacts with aldehydes to afford anti homoallylic alcohols when the reaction is carried out in THF, and preferentially syn products when the solvent is HMPA/THF=3:1. This simple control of anti versus syn dias
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