SYNTHESIS AND REARRANGEMENT OF FUNCTIONALIZED DISPIROUNDECANES A NEW ENTRY TO PROPELLANES

DOI: 10.1016/S0040-4039(00)95014-7

Source and publish data:

Tetrahedron Letters p. 5277 - 5280 (1985)

Update date:2022-08-30

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Authors:

Fitjer, Lutz

Kanschik, Andreas

Majewski, Marita

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Article abstract of DOI:10.1016/S0040-4039(00)95014-7

The functionalized dispiro<3.0.3.3>undecanes 6 and 7 undergo cascade rearrangements to yield the <3.3.3>propellanes 15 and 11, respectively.The formation of 15 proceeds via the bicyclic enone 16.

Full text of DOI:10.1016/S0040-4039(00)95014-7

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