Synthesis of the C6-C16 polyene fragment of ratjadone, a potent cytotoxic metabolite from Sorangium cellulosum

DOI: 10.1016/S0040-4039(99)00716-9

Source and publish data:

Tetrahedron Letters p. 4157 - 4160 (1999)

Update date:2022-08-16

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Authors:

Claus, Eckhard

Kalesse, Markus

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Article abstract of DOI:10.1016/S0040-4039(99)00716-9

The Pd-catalyzed synthesis of the polyene fragment of ratjadone is described. This strategy employs the Stille-coupling for the coupling of the tetrahydropyran subunit and the Suzuki coupling for attaching the unsaturated lactone to the polyene chain.

Full text of DOI:10.1016/S0040-4039(99)00716-9

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