Novel Electrocatalytic Procedure for the Oxidation of Alcohols, Aldehydes, Cyclic Ketones, and C-H Bonds Adjacent to Olefinic or Aromatic Groups

DOI: 10.1021/jo00199a043

Source and publish data:

Journal of Organic Chemistry p. 4972 - 4977 (1984)

Update date:2022-08-04

Topics:

Authors:

Thompson, Mark S.

Giovani, Wagner F. De

Moyer, Bruce A.

Meyer, Thomas J.

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Article abstract of DOI:10.1021/jo00199a043

A novel electrocatalytic procedure is described for the oxidation of primary and secondary alcohols, cyclic ketones, and C-H bonds adjacent to aromatic or olefinic groups.The procedure involves the use of the Ru^IVoxidant 2+ (trpy is 2,2',2''-terpyridine; bpy is 2,2'-bipyridine) in water at pH 6.8 or in dimethyl sulfone-water mixtures and is based on a electrochemical "shuttle" mechanism in which the Ru^IV complex is regenerated by electrochemical oxidation of II(trpy)(bpy)(H2O)>2+.

Full text of DOI:10.1021/jo00199a043

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