Tetrahedron p. 3117 - 3120 (1984)
Update date:2022-08-30
Topics:
Jenneskens, L. W.
Straten, J. W. van
Wolf, W. H. de
Bickelhaupt, F.
A new pyrolytic access to a metacyclophane has been found by the flash vacuum thermolysis of spiro<5,7>trideca-1,4-dien-3-one (4) which gave 9-hydroxy<7>metacyclophane (7), and 4-(6-heptenyl)phenol (8).The mechanism of formation of 7 and 8 from the intermediate diradical 6 is discussed.
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Doi:10.1016/0040-6031(89)87151-5
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(2013)Doi:10.1016/S0031-9422(99)00524-5
(2000)Doi:10.1021/acs.orglett.7b03539
(2018)Doi:10.1016/j.ejmech.2014.09.063
(2014)Doi:10.1007/BF00863173
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