Hydroxymethylation enantioselective d'alkyl benzenes chrome tricarbonyle ortho substitues

DOI: 10.1016/S0040-4020(01)87925-4

Source and publish data:

Tetrahedron p. 6011 - 6020 (1990)

Update date:2022-08-16

Topics:

Authors:

Lebibi Lebibi

Pelinski

Maciejewski

Brocard Brocard

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Article abstract of DOI:10.1016/S0040-4020(01)87925-4

Benzylic hydroxymethylation of chiral ortho alkyloxy, or dialkylamino, alkyl benzene tricarbonylchromium was found to show high or complete diastereoselectivity. Resolution of ortho methoxy ethyl benzene tricarbonylchromium provided (-)-(R)-2-(orthomethox

Full text of DOI:10.1016/S0040-4020(01)87925-4

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