Journal of the Chemical Society. Perkin transactions II p. 1197 - 1198 (1983)
Update date:2022-08-29
Topics:
Atkins, Paul J.
Gold, Victor
Wassef, Wasfy N.
The hydride Meisenheimer adduct of 2,4-dinitroaniline transfers hydride to 1,3,5-trinitrobenzene to form its corresponding hydride Meisenheimer adduct.The reaction is practically irreversible.In dilute solution in dimethyl sulphoxide it exhibits second-order kinetics and the observation of several sharp isosbestic points shows that it occurs without formation of any detectable intermediate species.
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Doi:10.1021/ja01250a001
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