ON THE GEOMETRIC REQUIREMENTS FOR CONCERTED 1,2-CARBONYL MIGRATION IN α,β-EPOXY KETONES

DOI: 10.1016/S0040-4039(00)98492-2

Source and publish data:

Tetrahedron Letters p. 985 - 988 (1985)

Update date:2022-08-16

Topics:

Authors:

Bach, Robert D.

Klix, Russel C.

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Article abstract of DOI:10.1016/S0040-4039(00)98492-2

The stabilizing influence of neighboring group participation by the carbonyl group in concerted 1,2-acyl migration is related to the ability of the molecule to assume a transition stage geometry resembling a cyclopropyloxenium ion.

Full text of DOI:10.1016/S0040-4039(00)98492-2

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