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| CAS No.: | 10025-97-5 |
|---|---|
| Name: | Iridium tetrachloride |
| Molecular Structure: | |
|
|
|
| Formula: | IrCl4 |
| Molecular Weight: | 334.032 |
| Synonyms: | Iridium(IV) chloride; |
| EINECS: | 233-048-8 |
| Solubility: | Soluble in water, alcohol and dilute hydrochloric acid. |
| Appearance: | dark-brown crystals |
| Hazard Symbols: | 34:; |
| Risk Codes: | 34 |
| Safety: | 26-36/37/39 |
| Transport Information: | UN 3260 |
| PSA: | 0.00000 |
| LogP: | -11.98400 |
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- 10025-97-5
iridium tetrachloride
| Conditions | Yield |
|---|---|
| With HCl with aq. regia; |
A
- 63976-47-6, 60183-09-7, 25456-36-4
trichloro triammine iridium(III)
B
- 10025-83-9
iridium (III) chloride
C
- 10025-97-5
iridium tetrachloride
| Conditions | Yield |
|---|---|
| With HCl In not given glowing in sealed tube over 100°C; |
- 92561-82-5, 119401-96-6
iridium tetrachloride monohydrate
- 10025-97-5
iridium tetrachloride
| Conditions | Yield |
|---|---|
| In solid in air; TG and DTA monitoring, X-ray diffraction anal.; |
- 10025-97-5
iridium tetrachloride
| Conditions | Yield |
|---|---|
| In solid in air; TG and DTA monitoring, X-ray diffraction anal.; |
- 10025-97-5
iridium tetrachloride
| Conditions | Yield |
|---|---|
| In water suspn. of IrCl4 and org. compd. in H2O heated at 150°C for 24 h; filtration, evapn., cooling; elem. anal.; | 60% |
- 10025-97-5
iridium tetrachloride
- 67-68-5
dimethyl sulfoxide
- 103992-30-9, 103992-31-0
{bis(dimethylsulphoxide)protium}{trans-bisdimethylsulphoxidetetrachloroiridate(III)}
| Conditions | Yield |
|---|---|
| With HCl In dimethyl sulfoxide; isopropyl alcohol IrCl4 reacted with concd. HCl in 2-propanol for 4 h at 55°C, soln. cooled to room temp., DMSO added; soln. was allowed to stand overnight, crystals filtered in air, washed with 2-propanol and ether, dried in vacuo; | 52% |
- 10025-97-5
iridium tetrachloride
| Conditions | Yield |
|---|---|
| With SOCl2 In diethyl ether stirred for 1 h; evapn., extn. (light petroleum), filtered, volume reduced, cooled to -30°C; | 25% |
- 10025-97-5
iridium tetrachloride
| Conditions | Yield |
|---|---|
| With SOCl2 In diethyl ether stirred for 1 h, kept at 10°C for 24 h; evapn., extn. (light petroleum), filtered, volume reduced, cooled to -30°C, recrystn. (light petroleum); | 23% |
| Conditions | Yield |
|---|---|
| Stage #1: magnesium oxide; oxygen; iridium tetrachloride In water at 20 - 120℃; for 2.5h; Stage #2: at 600℃; for 3h; |
- 10025-97-5
iridium tetrachloride
| Conditions | Yield |
|---|---|
| With hydrogen sulfide redn.; final treating with NaOH and ethanol; | |
| With V In water deposition of Ir after very long boiling;; | |
| With V In water deposition of Ir after very long boiling;; |
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Consensus Reports
Reported in EPA TSCA Inventory.
Specification
The IUPAC name of Iridium tetrachloride is tetrachloroiridium. With the CAS registry number 10025-97-5 and EINECS 233-048-8, it is also named as Iridium(IV) chloride. It is dark-brown crystals which is soluble in water. When heated to decomposition it emits toxic fumes of Cl−. In addition, this chemical should be sealed in the container and stored in dry place at the normal temperature.
The other characteristics of Iridium tetrachloride can be summarized as: (1)H-Bond Donor: 0; (2)H-Bond Acceptor: 0; (3)Rotatable Bond Count: 0; (4)Exact Mass: 334.835385; (5)MonoIsotopic Mass: 332.838335; (6)Topological Polar Surface Area: 0; (7)Heavy Atom Count: 5; (8)Formal Charge: 0; (9)Complexity: 19.1; (10)Isotope Atom Count: 0; (11)Covalently-Bonded Unit Count: 1.
When you are using this chemical, please be cautious about it as the following:
It can cause burns. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. If you want to contact this product, you must wear suitable protective clothing, gloves and eye/face protection.
People can use the following data to convert to the molecule structure.
1. SMILES:[Ir+3].[Cl-].[Cl-].[Cl-].[Cl-]
2. InChI:InChI=1/4ClH.Ir/h4*1H;/q;;;;+3/p-4
3. InChIKey:ZSKCYRQOFSOVNM-XBHQNQODAB
The following are the toxicity data which has been tested.
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| rat | LD50 | oral | 1560mg/kg (1560mg/kg) | Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 21(7), Pg. 55, 1977. |