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Cas Database

Name	Isopropylxanthic disulfide	EINECS	203-319-5
CAS No.	105-65-7	Density	1.275 g/cm³
PSA	133.24000	LogP	3.78760
Solubility	6.7μg/L at 20℃	Melting Point	54-56 °C(lit.)
Formula	C₈H₁₄O₂S₄	Boiling Point	316.5 °C at 760 mmHg
Molecular Weight	270.462	Flash Point	145.2 °C
Transport Information	N/A	Appearance	N/A
Safety	26-36	Risk Codes	31-36/37/38
Molecular Structure		Hazard Symbols	Xi
Synonyms	Formicacid, dithiobis[thio-, O,O-diisopropyl ester (6CI,8CI);Thioperoxydicarbonicacid ([(HO)C(S)]2S2), bis(1-methylethyl) ester (9CI);Bis(2-propyl)dixanthogen;Bis(O-isopropylxanthyl) disulfide;Diisopropyltetrathioperoxydicarbonate;Diisopropylxanthogen disulfide;Diproxide;NSC 402565;SanbitDIX;	Article Data	15

Isopropylxanthic disulfide Synthetic route

: 75-15-0
carbon disulfide

: 67-63-0
isopropyl alcohol

: 105-65-7
diisopropyl xanthogen disulfide

Conditions

Conditions	Yield
Stage #1: carbon disulfide; isopropyl alcohol With sodium hydroxide at 35 - 40℃; for 1.16667h; Stage #2: With chlorine for 1.83333h; Time;	95.2%

: 75-15-0
carbon disulfide

: 683-60-3
sodium isopropylate

: 105-65-7
diisopropyl xanthogen disulfide

Conditions

Conditions	Yield
With carbon tetrabromide at 20℃; for 1h; Cooling with ice;	51%

: 140-92-1
potassium isopropylxanthate

: 105-65-7
diisopropyl xanthogen disulfide

Conditions

Conditions	Yield
With iodine; potassium iodide In water for 24h;	40%
With iodine In water; isopropyl alcohol Yield given;
With iron(III) perchlorate In acetonitrile Ambient temperature; determination of amount by potentiometric or spectrophotometric titration;

: 115029-09-9
C15H15NO4S2

A: 3339-73-9
3-phthalimidopropanoic acid

B: 105-65-7
diisopropyl xanthogen disulfide

C: thioanhydride of phthalylalanine

Conditions

Conditions	Yield
In benzene for 1h; Irradiation;

alkali salt of/the/ isopropylxanthogenic acid: alkali salt of/the/ isopropylxanthogenic acid

: 105-65-7
diisopropyl xanthogen disulfide

Conditions

Conditions	Yield
With water; iodine in der Kaelte;
With sodium hypochlorite; water at 15 - 20℃;
With water; chloroamine-T
With bromocyane; water
With sodium hypochlorite; water at 15 - 20℃;

alkali salts of/the/ isopropylxanthogenic acid: alkali salts of/the/ isopropylxanthogenic acid

: 105-65-7
diisopropyl xanthogen disulfide

Conditions

Conditions	Yield
With chloroform; water; nitrosylchloride

: C4H7OS2

: 105-65-7
diisopropyl xanthogen disulfide

Conditions

Conditions	Yield
In acetonitrile Kinetics; recombination;

: 140-93-2
sodium isopropylxanthate

: 105-65-7
diisopropyl xanthogen disulfide

Conditions

Conditions	Yield
With sodium hypochlorite In water; isopropyl alcohol at 0℃; for 0.5h;	81.5 g

: bis[dichloro(pentamethylcyclopentadienyl)ruthenium(III)]

: 105-65-7
diisopropyl xanthogen disulfide

: 918828-87-2
[(η5-C5Me5)RuCl2(S2CO(i)Pr)]

Conditions

Conditions	Yield
In acetonitrile (N2); isopropylxanthic disulfide added to a soln. of Ru complex; filtered (silica gel), concd. (vac.), ether added, cooled to -30°C; elem. anal.;	89%

: 3947-62-4, 6207-76-7, 19235-21-3, 22554-70-7, 22860-22-6, 47339-09-3, 57884-82-9, 62057-79-8, 70191-05-8, 109525-54-4, 140147-37-1, 10343-06-3
2,3,4,5-tetra-O-acetyl-D-glucopyranose

: 105-65-7
diisopropyl xanthogen disulfide

: C18H26O10S2

Conditions

Conditions	Yield
With tributylphosphine; 4 A molecular sieve In toluene at 20℃;	87%

Isopropylxanthic disulfide Chemical Properties

IUPAC Name: O-isopropyl isopropoxy carbothioyl disulfanyl methanethioate
CAS: 105-65-7
EINECS: 203-319-5
Following is the Molecular Structure of Isopropyl xanthogen disulfide (105-65-7):

SMILES: S=C(SSC(=S)OC(C)C)OC(C)C
InChI: InChI=1/C8H14O2S4/c1-5(2)9-7(11)13-14-8(12)10-6(3)4/h5-6H,1-4H3
InChIKey: ZWWQICJTBOCQLA-UHFFFAOYAM
Std.InChI: InChI=1S/C8H14O2S4/c1-5(2)9-7(11)13-14-8(12)10-6(3)4/h5-6H,1-4H3
Std.InChIKey: ZWWQICJTBOCQLA-UHFFFAOYSA-N
Molecular Formula: C₈H₁₄O₂S₄
Molecular Weight: 270.46
Melting Point: 54-56℃(lit.)
Boiling Point: 316.5℃ at 760mmHg
Flash Point: 145.2℃
Molar Volume: 211.9cm³
Density: 1.275g/cm³
Index of Refraction: 1.605
Molar Refractivity: 73.09cm³
Surface Tension: 55.6dyne/cm
Polarizability: 28.97 10^-24cm³
Enthalpy of Vaporization: 53.56kJ/mol
Vapour Pressure: 0.000759mmHg at 25℃

Isopropylxanthic disulfide Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
rat	LDLo	oral	1500mg/kg (1500mg/kg)	LUNGS, THORAX, OR RESPIRATION: DYSPNEA GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS	National Technical Information Service. Vol. OTS0571751,

Isopropylxanthic disulfide Safety Profile

Hazard Codes: Xi Irritant.
Risk Statements: 31-36/37/38
R31: Contact with acids liberates toxic gas.
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36: Wear suitable protective clothing.
WGK: Germany 3
RTECS: XM6844300
Moderately toxic by ingestion.

Isopropylxanthic disulfide Specification

Isopropyl xanthogen disulfide (105-65-7),which also can be called for Bis(1-methylethyl)ester-thioperoxydicarbonicaci ; Bis(1-methylethyl)esterthioperoxydicarbonicacid ; Bis(2-propyl)dixanthogen ; Bis(isopropylxanthogen)disulfide ; Bis(o-isopropylxanthyl)disulfide ; Bis-iso-propylxanthogenate ; Diisopropyldixanthogen ; Diisopropylxanthogenatedisulfide .When Isopropyl xanthogen disulfide (105-65-7) was heated,it emits toxic vapors of SOx .

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