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Lithium methoxide

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Lithium methoxide

EINECS 212-737-7
CAS No. 865-34-9 Density 0.85g/mLat 20°C
PSA 23.06000 LogP 0.04670
Solubility Melting Point 500 °C
Formula CH3LiO Boiling Point 48.1 °C at 760 mmHg
Molecular Weight 37.97 Flash Point 11.1 °C
Transport Information UN 3274 3/PG 2 Appearance white powder
Safety 8-16-26-43-45-36/37/39 Risk Codes 14-17-34-39/23/24/25-36/38-23/24/25-11
Molecular Structure Molecular Structure of 865-34-9 (Methanol, lithium salt (1:1)) Hazard Symbols FlammableF,ToxicT,CorrosiveC
Synonyms

Lithiummethoxide (6CI,7CI);Methanol, lithium salt (8CI,9CI);Lithium methanolate;Lithium methylate;Methoxylithium;

 

Lithium methoxide Chemical Properties

Molecular structure of Methanol, lithium salt (1:1) (CAS NO.865-34-9) is:

Product Name: Methanol, lithium salt (1:1)
CAS Registry Number: 865-34-9
IUPAC Name: lithium methanolate
Molecular Weight: 37.97492 [g/mol]
Molecular Formula: CH3LiO
H-Bond Donor: 0
H-Bond Acceptor: 1 
EINECS: 212-737-7
Melting Point: 500 °C
Flash Point: 11.1 °C
Enthalpy of Vaporization: 35.21 kJ/mol
Boiling Point: 48.1 °C at 760 mmHg
Vapour Pressure: 265 mmHg at 25°C
Storage temp.: Flammables area
Sensitive: Moisture Sensitive
Stability: Stable, but reacts violently with water. Highly flammable. Store under dry inert gas.
Other Registry Number: 192823-90-8 ;224181-26-4 ;226904-79-6 ;719776-96-2 

Lithium methoxide Safety Profile

Hazard Codes: FlammableF,ToxicT,CorrosiveC
Risk Statements: 14-17-34-39/23/24/25-36/38-23/24/25-11 
R14 :Reacts violently with water. 
R17:Spontaneously flammable in air. 
R34:Causes burns. 
R39:Danger of very serious irreversible effects. 
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed. 
R11:Highly flammable.
Safety Statements: 8-16-26-43-45-36/37/39 
S8:Keep container dry. 
S16:Keep away from sources of ignition. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S43:In case of fire use ... (there follows the type of fire-fighting equipment to be used.) 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
RIDADR: UN 3274 3/PG 2
WGK Germany: 3
F: 3-10-23
TSCA: Yes
HazardClass: 4.2
PackingGroup: II

Lithium methoxide Specification

 Methanol, lithium salt (1:1) , its cas register number is 865-34-9. It also can be called Lithium methanolate ; Methanol, lithium salt .It is a white powder.

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