Related Products
- Methyl 1-Benzyl-5-oxopyrrolidine-3-carboxylate
- Methyl (((methoxymethylphosphinothioyl)thio)acetyl)methylcarbamate
- Methyl (+)-(3R)-7-[4-(4-fluorophenyl)-6-isopropyl-2-(N-methyl-N-methanesulfonylamino)pyrimidin-5-yl]-3-hydroxy-5-oxo-(6E)-heptenoate
- Methyl (2-amino-5-methyl-1,3-thiazol-4-yl)acetate
- Methyl (2-chloromethyl)oxazole-4-carboxylate
- Methyl (2E)-3-(4-methylphenyl)propenoate
- Methyl (2E)-3-cyclohexylprop-2-enoate
- Methyl (2R)-2-[(tert-butoxycarbonyl)amino]-3-iodopropanoate
- Methyl (2R)-2-[4-(2,4-dichlorophenoxy)phenoxy]propanoate
- Methyl (2R)-2-amino-2-cyclohexylethanoate hydrochloride
- 619-45-4Benzoic acid, 4-amino-,methyl ester
- 61948-60-5Quinazoline,2,4-dichloro-8-methoxy-
- 61948-83-2Benzoic acid,5-ethoxy-4-methoxy-2-nitro-
- 61948-85-4Benzoic acid,2-amino-3,4,5-trimethoxy-
- 61-94-93-Pyridinecarboxylicacid, 1,2,5,6-tetrahydro-1-methyl-, methyl ester, hydrochloride (1:1)
- 61949-16-4α-D-Glucopyranose,2-(benzoylamino)-2-deoxy-
- 61949-75-52H-Pyran-2-one,tetrahydro-4-phenyl-
- 61949-83-51-Aminoindane
- 619-50-1Benzoic acid, 4-nitro-,methyl ester
- 61950-59-2Somatostatin (sheep),8-D-tryptophan-14-D-cysteine- (9CI)
Hot Products
- 104987-11-3Tacrolimus
- 141-53-7Sodium formate
- 8001-54-5Quaternary ammonium compounds, alkylbenzyldimethyl, chlorides
- 9003-39-8Povidone
- 10161-34-9Trenbolone acetate
- 402957-28-2Telaprevir
- 68-19-9Cyanocobalamin
- 7631-86-9Silicon dioxide
- 302-79-4Tretinoin
- 77-92-9Citric acid
|
Basic Information |
|
Post buying leads |
|
Suppliers |
|
Cas Database |
| Name |
METHYL 4-IODOBENZOATE |
EINECS | 210-597-1 |
| CAS No. | 619-44-3 | Density | 1.753 g/cm3 |
| PSA | 26.30000 | LogP | 2.07780 |
| Solubility | N/A | Melting Point |
113-117 °C |
| Formula | C8H7IO2 | Boiling Point | 276.1 °C at 760 mmHg |
| Molecular Weight | 262.047 | Flash Point | 120.8 °C |
| Transport Information | UN 3082 | Appearance | beige to pale pink crystalline powder |
| Safety | 37/39-26-61 | Risk Codes | 36/37/38-51/53 |
| Molecular Structure |
|
Hazard Symbols |
 Xi，  N
|
| Synonyms |
Benzoicacid, p-iodo-, methyl ester (6CI,7CI,8CI);4-(Carbomethoxy)iodobenzene;4-(Methoxycarbonyl)-1-iodobenzene;4-(Methoxycarbonyl)iodobenzene;4-(Methoxycarbonyl)phenyl iodide;4-Iodobenzoic acid methyl ester;Methyl p-iodobenzoate;NSC 9393;p-(Methoxycarbonyl)phenyliodide;p-Iodobenzoic acid methyl ester; |
Article Data | 95 |
METHYL 4-IODOBENZOATE Synthetic route
Conditions
| Conditions | Yield |
|---|---|
| With acetyl chloride at 60℃; for 12h; | 100% |
| With sulfuric acid for 30h; Reflux; | 99% |
| With sulfuric acid Reflux; | 99% |
Conditions
| Conditions | Yield |
|---|---|
| With N-chloro-succinimide In methanol; acetic acid to a soln. of Sn-compd. in MeOH was added NaI in MeOH, then Na(125)I was added (10% stoichiometric amount of NaI/Na(125)I), addn. of AcOH followed by addn. of NCS in MeOH, the mixture was stirred at 25°C for 20 min; the reaction was monitored by use of HPLC equipped with a UV detector, the yield was calculated by HPLC analysis of a solution of known concn., the established yield is the radiochemical yield; | 98% |
| With N-chloro-succinimide In methanol; acetic acid to a soln. of Sn-compd. in MeOH was added NaI in MeOH, then Na(125)I was added (100% stoichiometric amount of NaI/Na(125)I), addn. of AcOH followed by addn. of NCS in MeOH, the mixture was stirred at 25°C; the reaction was monitored by use of HPLC equipped with a UV detector, the yield was calculated by HPLC analysis of a solution of known concn., the established yield is the radiochemical yield; | 98% |
- 619-44-3
methyl 4-iodobenzoate
Conditions
| Conditions | Yield |
|---|---|
| With iodine In various solvent(s) at 100℃; for 9h; | 97% |
- 77726-96-6
methyl 4-(3,3-diethyltriaz-1-en-1-yl)benzoate
- 74-88-4
methyl iodide
- 619-44-3
methyl 4-iodobenzoate
Conditions
| Conditions | Yield |
|---|---|
| at 110 - 120℃; for 6h; | 97% |
Conditions
| Conditions | Yield |
|---|---|
| With dihydrogen peroxide at 20℃; for 20h; | 97% |
| With oxygen; potassium carbonate at 65℃; for 3h; Catalytic behavior; | 82 %Chromat. |
Conditions
| Conditions | Yield |
|---|---|
| With N-chloro-succinimide In methanol; acetic acid to a soln. of B-compd. in MeOH was added NaI in MeOH, then Na(125)I was added (100% stoichiometric amount of NaI/Na(125)I), addn. of AcOH followed by addn. of two equivalents of NCS in MeOH, the mixture was stirred at 25°C for 24 h; the reaction was monitored by use of HPLC equipped with a UV detector, the yield was calculated by HPLC analysis of a solution of known concn., the established yield is the radiochemical yield; | 96% |
| With N-chloro-succinimide In methanol; acetic acid to a soln. of B-compd. in MeOH was added NaI in MeOH, then Na(125)I was added (100% stoichiometric amount of NaI/Na(125)I), addn. of AcOH followed by addn. of NCS in MeOH, the mixture was stirred at 25°C for 20 h; the reaction was monitored by use of HPLC equipped with a UV detector, the yield was calculated by HPLC analysis of a solution of known concn., the established yield is the radiochemical yield; | 70% |
| With N-chloro-succinimide In methanol; acetic acid to a soln. of B-compd. in MeOH was added NaI in MeOH, then Na(125)I was added (100% stoichiometric amount of NaI/Na(125)I), addn. of AcOH followed by addn. of NCS in MeOH, the mixture was stirred at 25°C for 3 h; the reaction was monitored by use of HPLC equipped with a UV detector, the yield was calculated by HPLC analysis of a solution of known concn., the established yield is the radiochemical yield; | 60% |
| With N-chloro-succinimide In methanol; acetic acid to a soln. of B-compd. in MeOH was added NaI in MeOH, then Na(125)I was added (10% stoichiometric amount of NaI/Na(125)I), addn. of AcOH followed by addn. of NCS in MeOH, the mixture was stirred at 25°C for 20 min; the reaction was monitored by use of HPLC equipped with a UV detector, the yield was calculated by HPLC analysis of a solution of known concn., the established yield is the radiochemical yield; | >99 |
Conditions
| Conditions | Yield |
|---|---|
| With copper(II) bis(trifluoromethanesulfonate) at 20℃; for 16h; | 96% |
Conditions
| Conditions | Yield |
|---|---|
| With triethylamine at 100℃; for 24h; Inert atmosphere; | 96% |
Conditions
| Conditions | Yield |
|---|---|
| In methanol at 20℃; | 95% |
Conditions
| Conditions | Yield |
|---|---|
| With triethylamine In dichloromethane at 0℃; for 0.5h; | 93% |
| Stage #1: 4-iodobenzoic acid chloride With pyridine In dichloromethane at 20℃; for 16h; Stage #2: With pyridinium p-toluenesulfonate In toluene at 50℃; for 16h; Stage #3: methanol With sodium amide In tetrahydrofuran for 0.5h; Further stages.; |
METHYL 4-IODOBENZOATE Chemical Properties
Molecular Formula: C8H7IO2 
Formula Weight: 262.04
Synonyms:
Iodobenzoicacidmethylester, 4-p-(Methoxycarbonyl)phenyl iodide, 4-(Carbomethoxy)iodobenzene, 4-(Methoxycarbonyl)phenyl iodide, METHYL 4-IODOBENZENECARBOXYLATE, METHYL 4-IODOBENZOATE
Melting point: 113-117 °C
Flash Point: 120.8 °C
Boiling Point: 276.1 °C at 760 mmHg
Density of METHYL 4-IODOBENZOATE (619-44-3): 1.753 g/cm3
Vapour Pressure: 0.00491 mmHg at 25°C
Index of Refraction: 1.597
Form of METHYL 4-IODOBENZOATE (619-44-3): Crystalline
Formula Weight: 262.04
Synonyms:
Iodobenzoicacidmethylester, 4-p-(Methoxycarbonyl)phenyl iodide, 4-(Carbomethoxy)iodobenzene, 4-(Methoxycarbonyl)phenyl iodide, METHYL 4-IODOBENZENECARBOXYLATE, METHYL 4-IODOBENZOATE
Melting point: 113-117 °C
Flash Point: 120.8 °C
Boiling Point: 276.1 °C at 760 mmHg
Density of METHYL 4-IODOBENZOATE (619-44-3): 1.753 g/cm3
Vapour Pressure: 0.00491 mmHg at 25°C
Index of Refraction: 1.597
Form of METHYL 4-IODOBENZOATE (619-44-3): Crystalline
METHYL 4-IODOBENZOATE Safety Profile
Safety: WARNING: Irritates lungs, eyes, skin
Hazard Codes : Xi: Irritant; N: Dangerous for the environment
Risk Statements : 36/37/38: Irritating to eyes, respiratory system and skin
51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Safety Statements : 37/39: Wear suitable gloves and eye/face protection
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
61: Avoid release to the environment. Refer to special instructions safety data sheet
RIDADR : UN 3082
Hazard Codes : Xi: Irritant; N: Dangerous for the environment
Risk Statements : 36/37/38: Irritating to eyes, respiratory system and skin
51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Safety Statements : 37/39: Wear suitable gloves and eye/face protection
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
61: Avoid release to the environment. Refer to special instructions safety data sheet
RIDADR : UN 3082
METHYL 4-IODOBENZOATE Specification
Storage: Store in cool, dry conditions in well sealed containers. Store away from oxidizing agents.
Post a RFQ
1
What can I do for you?
Get Best Price
Get Best Price for 619-44-3
Methyl 4-iodobenzoate
