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7681-82-5

Basic Information
CAS No.: 7681-82-5
Name: Sodium iodide (NaI)
Article Data: 319
Cas Database
Molecular Structure:
Molecular Structure of 7681-82-5 (Sodium iodide (NaI))
Formula: NaI
Molecular Weight: 149.894
Synonyms: Sodiumiodide (8CI);Anayodin;Ioduril;NSC 77388;Sodium monoiodide;Soiodin;Sodium iodid bp grade;Sodiumiodide (NaI);Sodium iodide;
EINECS: 231-679-3
Density: 3.66 g/cm3
Melting Point: 661 °C
Boiling Point: 1300 °C
Flash Point: 1300-1304°C
Solubility: soluble in water, ethanol, methanol, glycerol and acetone
Appearance: white crystalline salt
Hazard Symbols: IrritantXi
Risk Codes: 36/37/38
Safety: 26
Transport Information: N/A
PSA: 0.00000
LogP: -2.99600
Synthetic route
421-59-0

trifluoromethyldiiodophosphine

A

sodium phosphite

B

75-46-7

trifluoromethan

C

7681-82-5

sodium iodide

Conditions
ConditionsYield
With NaOH In water 20°C (24 h); hydrolysis;A n/a
B 99.5%
C 100%
1020-31-1

3,5-Di-tert-butylcatechol

13450-91-4

gallium(III) iodide

A

gallium(III) tris(3,5-di-tert-butyl-1,2-semibenzoquinonate)

B

7681-82-5

sodium iodide

Conditions
ConditionsYield
With NaOH In toluene byproducts: H2; N2 atmospher; treatment of catechol and NaOH in toluene (stirring, 30 min), dropwise addn. of GaI in toluene (4 h); sepn. of NaI (filtration off, drying), collectin of Ga-complex by evapn. of filtrate;A 97%
B n/a
108-89-4

picoline

13510-35-5

indium(III) iodide

4679-12-3, 61373-02-2

sodium 3,5-di-tert-butyl-o-benzosemiquinolate

[InI(((CH3)3C)2C6H2O2)(CH3C5H4N)2]2*2(CH3)2NCHO

B

7681-82-5

sodium iodide

Conditions
ConditionsYield
With NaH In tetrahydrofuran byproducts: H2; N2, soln. of semiquinonate sodium salt added dropwise over 1 h to a soln. of In-salt, stirred for 2 h at room temp., NaI removed by filtrn., excess 4-picoline added to the filtrate; collected, dried, recrystd. (DMF); elem. anal.; further intermediates and other products. discussed;A 50%
B 92%

bis(cyclopentadienyl)zirconium diiodide

128-04-1

sodium dimethyldithiocarbamate

A

bis(η5-cyclopentadienyl)(N,N-dimethyldithiocarbamato)iodozirconium(IV)

B

7681-82-5

sodium iodide

Conditions
ConditionsYield
In dichloromethane Kinetics; React. of starting complexes (CH2Cl2, 12 h, room temp., anhydrous conditions, dry Ar).; Crystn. from CH2Cl2 under hexane (-15°C), elem. anal., variable-temp. NMR spectroscopy.;A 88%
B n/a

Ma[W(CO)3(η5-cyclopentadienyl)]*2(DME)

(C6H5)2Sn(C(CH3)3)I

A

1-tert-butyl-1-((η(5)-cyclopentadienyl)tricarbonyltungsten)diphenyltin

B

7681-82-5

sodium iodide

Conditions
ConditionsYield
In tetrahydrofuran; toluene N2-atmosphere; stirring (room temp., overnight), evapn. (reduced pressure), toluene addn., stirring (1 h), filtering, concg.; n-hexane addn., crystn. (fridge); elem. anal.;A 83%
B n/a
15602-40-1

sodium hexacarbonyltantalate*THF

18820-83-2

pyridine hydroiodide

A

112713-58-3

tetracarbonyl{1,2-bis(diphenylphosphino)ethane}iodotantalum

B

7681-82-5

sodium iodide

Conditions
ConditionsYield
With C2H4(P(C6H5)2)2 In tetrahydrofuran; toluene byproducts: C5H5N, CO, H2; Treating of suspn. of diphos and (H-py)I in THF with Ta-complex at room temp. under a CO atmosphere.; Immediate react. with evolution of CO and H2 (gas chromy.) obsd. Stirring (2 h, room temp.), removal of THF (vac., room temp.), dissolving of residue (toluene, CO), stirring (2 h), filtn., treating with n-heptane. Sepn. of microcryst., elem. anal.;A 79%
B n/a
15602-39-8

sodium{(THF)2.3} hexacarbonylniobate

18820-83-2

pyridine hydroiodide

A

112713-57-2

tetracarbonyl{1,2-bis(diphenylphosphino)ethane}iodoniobium

B

7681-82-5

sodium iodide

Conditions
ConditionsYield
With C2H4(P(C6H5)2)2 In tetrahydrofuran; toluene byproducts: C5H5N, CO, H2; Treating of suspn. of diphos and (H-py)I in THF with Nb-complex at room temp. under a CO atmosphere.; Immediate react. with evolution of CO and H2 (gas chromy.) obsd. Stirring (2 h, room temp.), removal of THF (vac., room temp.), dissolving of residue (toluene, CO), stirring (2 h), filtn., treating with n-heptane. Sepn. of microcryst., elem. anal.;A 76%
B n/a

[(CH(NC6H3(CH(CH3)2)2)2)2SmI2(C4H8O)](1-)*Na(1+)*5C4H8O=[(CH(NC6H3(CH(CH3)2)2)2)2SmI2(C4H8O)](Na(C4H8O)5)

A

samarium triiodide(THF)3.5

B

[Sm(N,N′-bis(2,6-diisopropylphenyl)formamidinate)3]

C

7681-82-5

sodium iodide

Conditions
ConditionsYield
In hexane dissolved in warm hexane (35°C); filtered, volatiles removed (vac.), extd. (toluene), cooled to -10°C overnight; elem. anal.;A n/a
B 72%
C n/a
16940-66-2

sodium tetrahydroborate

A

B

C

diborane

diborane

Conditions
ConditionsYield
In dimethoxyethane (DME) at 20℃; for 1h;A n/a
B n/a
C 70%
16940-66-2

sodium tetrahydroborate

33797-51-2

eschenmoser's salt

A

1231953-83-5

trimethylamine borane

B

7681-82-5

sodium iodide

Conditions
ConditionsYield
In diethyl ether React. of starting materials in Et2O (vac. distd., -196°C), warming to 25°C, and stirring overnight.; Distn. of volatile materials into a -196°C U-trap and fractionalcondensation at -68 and -196°C yields Me3N*BH3 in the -68°C trap.;A 45.6%
B n/a
In neat (no solvent) Mixing of starting powders with vigorous stirring at 25°C under N2.; Condensing of volatile materials in a -196°C U-trap, results after 2 h in a small amt. of a solid.;
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    Name: Sodium iodide (NaI) CAS No.: 7681-82-5 Formula: NaI Molecular Weight: 149.89 Synonyms: Sodiumiodide (8CI);Anayodin;Ioduril;NSC 77388;Sodium monoiodide;Soiodin;Sodium iodid bp grade;Sodiumiodide (NaI);Sodium iodide; EINECS: 231-679-3

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Reported in EPA TSCA Inventory.

Specification

The Sodium iodide, with the CAS registry number 7681-82-5, is also known as Sodium monoiodide. It belongs to the product categories of Inorganics; Analytical Reagents for General Use; Essential Chemicals; Reagent Plus; Routine Reagents; Inorganic Salts; Synthetic Reagents; Pharmacopoeia (USP); Pharmacopoeial Inorganics; Crystal Grade Inorganics; Salts; Sodium Salts; Sodium Metal and Ceramic Science; Metal and Ceramic Science; ACS Grade Synthetic Reagents; Chemical Synthesis; Crystal Grade Inorganics; Inorganic Salts; Materials Science. Its EINECS number is 231-679-3. This chemical's molecular formula is NaI and molecular weight is 149.89. What's more, its systematic name is Sodium iodide. Its classification codes are: (1)Human Data; (2)Reproductive Effect; (3)Skin / Eye Irritant; (4)Supplement [iodine]. This chemical should be sealed and stored in a cool and dry place. Moreover, it should be protected from light. It is used in radiation detection, treatment of iodine deficiency, and as a reactant in the Finkelstein reaction. Sodium iodide is manufactured from the reaction between iodine and sodium hydroxide.

When you are using this chemical, please be cautious about it as the following:
This chemical is irritating to eyes, respiratory system and skin. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1)SMILES: [Na+].[I-]
(2)Std. InChI: InChI=1S/HI.Na/h1H;/q;+1/p-1
(3)Std. InChIKey: FVAUCKIRQBBSSJ-UHFFFAOYSA-M

The toxicity data is as follows:  

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
dog LDLo intravenous 760mg/kg (760mg/kg)   "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1289, 1935.
man TDLo oral 100uL/kg/14D- (.1mL/kg) ENDOCRINE: OTHER CHANGES

BLOOD: "CHANGES IN SERUM COMPOSITION (E.G., TP, BILIRUBIN, CHOLESTEROL)"
Clinical Endocrinology Vol. 28, Pg. 283, 1988.
mouse LD50 intraperitoneal 430mg/kg (430mg/kg)   Proceedings of the Society for Experimental Biology and Medicine. Vol. 115, Pg. 551, 1964.
mouse LD50 oral 1gm/kg (1000mg/kg)   "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 105, 1982.
rabbit LDLo oral 2362mg/kg (2362mg/kg)   Journal of Pharmacology and Experimental Therapeutics. Vol. 30, Pg. 407, 1927.
rat LD50 intravenous 1060mg/kg (1060mg/kg)   Naunyn-Schmiedeberg's Archiv fuer Experimentelle Pathologie und Pharmakologie. Vol. 222, Pg. 584, 1954.
rat LD50 oral 4340mg/kg (4340mg/kg)   "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha, Czechoslovakia, 1972Vol. -, Pg. 21, 1972.