|
Basic Information |
|
Post buying leads |
|
Suppliers |
|
Cas Database |
- Name Methyl benzoylformate
- EINECS239-263-3
- CAS No. 15206-55-0
- Density1.164 g/cm3
- PSA43.37000
- LogP1.04230
- Solubility2g/L at 20℃
- Melting Point16 °C
- FormulaC9H8O3
- Boiling Point247 °C at 760 mmHg
- Molecular Weight164.161
- Flash Point103.8 °C
- Transport InformationN/A
- Appearancelight yellow liquid
- Safety24/25
- Risk CodesN/A
- Molecular Structure
- Hazard SymbolsN/A
- SynonymsN/A
- Article Data291
Methyl benzoylformate Synthetic route
- 4358-87-6
(RS)-methyl mandelate
- 15206-55-0
methyl 2-oxo-2-phenylacetate
| Conditions | Yield |
|---|---|
| With 2,2,6,6-tetramethyl-piperidine-N-oxyl; oxygen; copper(I) bromide dimethylsulfide complex In chlorobenzene at 90℃; for 7h; | 100% |
| With sodium hydrogencarbonate; sodium bromide In dichloromethane at 20℃; Electrochemical reaction; | 99% |
| With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; calcium methylate In acetonitrile at 0 - 20℃; | 99% |
- 4249-72-3
2-phenoxy-1-phenylethanol
A
- 93-58-3
benzoic acid methyl ester
B
- 15206-55-0
methyl 2-oxo-2-phenylacetate
C
- 108-95-2
phenol
| Conditions | Yield |
|---|---|
| With oxygen In methanol at 80 - 120℃; | A 66% B 34% C 100% |
- 67-56-1
methanol
- 21132-27-4
2-(4-methoxyphenyl)-4-phenyl-1,3-dithiol-1-ium-5-olate
A
- 15206-55-0
methyl 2-oxo-2-phenylacetate
B
- 15088-73-0
4-methoxybenzoic dithioperoxyanhydride
| Conditions | Yield |
|---|---|
| With 4,5,6,7-tetrachloro-2',4',5',7'-tetraiodofluorescein disodium salt; oxygen In methanol; benzene for 1h; Irradiation; | A 43% B 99% |
- 67-56-1
methanol
- 20850-89-9
2,5-diphenyl-1,3-dithiolylium-4-olate
A
- 15206-55-0
methyl 2-oxo-2-phenylacetate
B
- 644-32-6
dibenzoyl disulfide
| Conditions | Yield |
|---|---|
| With 4,5,6,7-tetrachloro-2',4',5',7'-tetraiodofluorescein disodium salt; oxygen In methanol; benzene at 10℃; for 1.25h; Irradiation; | A 28% B 99% |
- 21132-27-4
2-(4-methoxyphenyl)-4-phenyl-1,3-dithiol-1-ium-5-olate
A
- 15206-55-0
methyl 2-oxo-2-phenylacetate
B
- 15088-73-0
4-methoxybenzoic dithioperoxyanhydride
| Conditions | Yield |
|---|---|
| With 4,5,6,7-tetrachloro-2',4',5',7'-tetraiodofluorescein disodium salt; oxygen In methanol; benzene for 1h; Irradiation; | A 43% B 99% |
- 20850-89-9
2,5-diphenyl-1,3-dithiolylium-4-olate
A
- 15206-55-0
methyl 2-oxo-2-phenylacetate
B
- 644-32-6
dibenzoyl disulfide
| Conditions | Yield |
|---|---|
| With 4,5,6,7-tetrachloro-2',4',5',7'-tetraiodofluorescein disodium salt; oxygen In methanol; benzene at 10℃; for 1.25h; Irradiation; | A 28% B 99% |
- 614-27-7
methyl 3-oxo-3-phenylpropionate
- 15206-55-0
methyl 2-oxo-2-phenylacetate
| Conditions | Yield |
|---|---|
| With aluminum (III) chloride; Oxone In water at 20℃; for 24h; | 98% |
| With iodine; dimethyl sulfoxide; copper(ll) bromide for 8h; Schlenk technique; Heating; | 81% |
- 51863-47-9
(diethoxyphosphoryl)-phenyl-acetic acid methyl ester
- 15206-55-0
methyl 2-oxo-2-phenylacetate
| Conditions | Yield |
|---|---|
| Stage #1: (diethoxyphosphoryl)-phenyl-acetic acid methyl ester With sodium t-butanolate In N,N-dimethyl-formamide at 25℃; for 0.0833333h; Inert atmosphere; Stage #2: With oxygen In N,N-dimethyl-formamide at 25℃; for 8h; stereoselective reaction; | 96% |
| Conditions | Yield |
|---|---|
| With hydrogen-type cation exchange resin at 80℃; under 675.068 Torr; for 2h; Pressure; Temperature; | 95.5% |
| With sulphate-doped anatase In cyclohexane Concentration; Reflux; Industrial scale; | 92.5% |
| With chloro-trimethyl-silane In tetrahydrofuran at 22℃; for 72h; | 89% |
| Conditions | Yield |
|---|---|
| Stage #1: benzoyl cyanide With sulfuric acid; tetrabutylammomium bromide; ammonium chloride In para-xylene at 20 - 40℃; for 2h; Stage #2: methanol In para-xylene at 40 - 90℃; for 3.5h; Reagent/catalyst; Temperature; Solvent; | 95% |
| With hydrogenchloride Behandeln mit Wasser; | |
| With sulfuric acid; acetic anhydride; sodium bromide 1.) 70 deg C; Yield given. Multistep reaction; | |
| at 55 - 65℃; for 1h; | 449 g |
Methyl benzoylformate Chemical Properties
Structure of Methyl benzoylformate (CAS NO.15206-55-0):
IUPAC Name: methyl 2-oxo-2-phenylacetate
Empirical Formula: C9H8O3
Molecular Weight: 164.158
EINECS: 239-263-3
Index of Refraction: 1.517
Molar Refractivity: 42.68 cm3
Molar Volume: 140.9 cm3
Polarizability: 16.92×10-24cm3
Surface Tension: 41.1 dyne/cm
Density: 1.164 g/cm3
Flash Point: 103.8 °C
Enthalpy of Vaporization: 48.41 kJ/mol
Melting Point: 16°C
Boiling Point: 247 °C at 760 mmHg
Vapour Pressure: 0.0263 mmHg at 25°C
Physical Appearance: clear yellow liquid
Product Categories: Aromatic Esters
Synonyms of Methyl benzoylformate (CAS NO.15206-55-0): Benzeneacetic acid, alpha-oxo-, methyl ester ; Glyoxylic acid, phenyl-, methyl ester ; Methyl oxophenylacetate ; Methyl phenylglyoxylate ; Phenylglyoxylic acid, methyl ester
Methyl benzoylformate Safety Profile
Safety Statements: 24/25
S24/25:Avoid contact with skin and eyes.
WGK Germany: 1
HS Code: 29183000
What can I do for you?
Get Best Price
- Methyl 1-Benzyl-5-oxopyrrolidine-3-carboxylate
- Methyl (((methoxymethylphosphinothioyl)thio)acetyl)methylcarbamate
- Methyl (+)-(3R)-7-[4-(4-fluorophenyl)-6-isopropyl-2-(N-methyl-N-methanesulfonylamino)pyrimidin-5-yl]-3-hydroxy-5-oxo-(6E)-heptenoate
- Methyl (2E)-3-(4-methylphenyl)propenoate
- Methyl (2E)-3-cyclohexylprop-2-enoate
- Methyl (2R)-2-[(tert-butoxycarbonyl)amino]-3-iodopropanoate
- Methyl (2R)-2-[4-(2,4-dichlorophenoxy)phenoxy]propanoate
- Methyl (2R)-2-amino-2-cyclohexylethanoate hydrochloride
- Methyl (2R)-2-bromo-2-(2-chlorophenyl)acetate
- Methyl (2R,3S)-3-(4-methoxyphenyl)-2-oxiranecarboxylate
- 1520-70-3Ethanesulfonamide
- 152089-12-81-Azetidinecarboxylicacid, 3-(1-ethoxyethoxy)-2-oxo-4-phenyl-, 1,1-dimethylethyl ester
- 15209-52-62-Acetoxybenzoic acid, compound with 2-amino-2-(hydroxymethyl)propane-1,3-diol (1:1)
- 1520-96-3Perylene-1,2,3,4,5,6,7,8,9,10,11,12-d12
- 152-11-4Verapamil hydrochloride
- 15212-03-0Phenol, 2-methoxy-, acetate
- 152120-54-2Carbamic acid,N-[[[(1,1-dimethylethoxy)carbonyl]amino]-1H-pyrazol-1-ylmethylene]-,1,1-dimethylethyl ester
- 152121-41-01-(4-fluorophenyl)-2-pyridin-4-ylethane-1,2-dione
- 152121-47-6Pyridine,4-[4-(4-fluorophenyl)-2-[4-(methylsulfinyl)phenyl]-1H-imidazol-5-yl]-
- 152121-53-4Pyridine, 4-[4-(4-fluorophenyl)-2-(4-nitrophenyl)-1H-imidazol-5-yl]-
Hot Products
- 104987-11-3Tacrolimus
- 141-53-7Sodium formate
- 8001-54-5Quaternary ammonium compounds, alkylbenzyldimethyl, chlorides
- 9003-39-8Povidone
- 10161-34-9Trenbolone acetate
- 402957-28-2Telaprevir
- 68-19-9Cyanocobalamin
- 7631-86-9Silicon dioxide
- 302-79-4Tretinoin
- 77-92-9Citric acid