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O-Benzylhydroxylamine

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Name

O-Benzylhydroxylamine

EINECS 220-249-0
CAS No. 622-33-3 Density 1.063 g/cm3
PSA 35.25000 LogP 1.77720
Solubility N/A Melting Point 238 °C (subl.)(lit.)
Formula C7H9NO Boiling Point 237.5 °C at 760 mmHg
Molecular Weight 123.155 Flash Point 113.1 °C
Transport Information N/A Appearance Clear colorless liquid
Safety 22-24/25 Risk Codes 36/37/38
Molecular Structure Molecular Structure of 622-33-3 (O-Benzylhydroxylamine) Hazard Symbols IrritantXi
Synonyms

Benzyloxyamine(6CI,7CI);Hydroxylamine, O-benzyl- (8CI);O-(Phenylmethyl)hydroxylamine;O-Benzyloxyamine;SNR 1635;a-(Aminooxy)toluene;

Article Data 84

O-Benzylhydroxylamine Specification

The CAS registry number of Hydroxylamine,O-(phenylmethyl)- is 622-33-3. The systematic name is O-benzylhydroxylamine. In addition, the molecular formula is C7H9NO and the molecular weight is 123.15. It is also called [(aminooxy)methyl]benzene. What's more, it is a kind of clear colorless liquid and belongs to the class of Polyamines. It should be stored in a cool and dry place.

Physical properties about this chemical are: (1)ACD/LogP: 1.55; (2)ACD/LogD (pH 5.5): 1.48; (3)ACD/LogD (pH 7.4): 1.55; (4)ACD/BCF (pH 5.5): 7.62; (5)ACD/BCF (pH 7.4): 8.82; (6)ACD/KOC (pH 5.5): 142.82; (7)ACD/KOC (pH 7.4): 165.23; (8)#H bond acceptors: 2; (9)#H bond donors: 2; (10)#Freely Rotating Bonds: 3; (11)Polar Surface Area: 12.47 Å2; (12)Index of Refraction: 1.542; (13)Molar Refractivity: 36.44 cm3; (14)Molar Volume: 115.7 cm3; (15)Polarizability: 14.44 ×10-24cm3; (16)Surface Tension: 40.8 dyne/cm; (17)Density: 1.063 g/cm3; (18)Flash Point: 113.1 °C; (19)Enthalpy of Vaporization: 47.44 kJ/mol; (20)Boiling Point: 237.5 °C at 760 mmHg; (21)Vapour Pressure: 0.0446 mmHg at 25°C.

Preparation of Hydroxylamine,O-(phenylmethyl)-: it can be prepared by N-benzyloxy-phthalimide. This reaction will need reagent hydrazine and solvent ethanol. The reaction time is 4 hours by heating. The yield is about 98%.

Hydroxylamine,O-(phenylmethyl)- can be prepared by N-benzyloxy-phthalimide

Uses of Hydroxylamine,O-(phenylmethyl)-: it can react with carbonyl dichloride to get N,N'-bis-benzyloxy-urea. This reaction will need solvents toluene and tetrahydrofuran. The reaction time is 5 hours at reaction temperature of 0-20 °C. The yield is about 65%.

Hydroxylamine,O-(phenylmethyl)- can react with carbonyl dichloride to get N,N'-bis-benzyloxy-urea

When you are using this chemical, please be cautious about it as the following:
It is irritating to eyes, respiratory system and skin. During using it, you should avoid contact with skin and eyes. In addition, do not breathe dust.

You can still convert the following datas into molecular structure:
(1)SMILES: O(N)Cc1ccccc1
(2)InChI: InChI=1/C7H9NO/c8-9-6-7-4-2-1-3-5-7/h1-5H,6,8H2
(3)InChIKey: XYEOALKITRFCJJ-UHFFFAOYAU

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