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Cas Database |
| Name |
Perfluoro-1-iodohexane |
EINECS | 206-586-6 |
| CAS No. | 355-43-1 | Density | 2.05 g/cm3 |
| PSA | 0.00000 | LogP | 5.11770 |
| Solubility | insoluble in water | Melting Point |
-45 °C |
| Formula | C6F13I | Boiling Point | 117.096 °C at 760 mmHg |
| Molecular Weight | 445.95 | Flash Point | 44.982 °C |
| Transport Information | UN 2810 | Appearance | liquid |
| Safety | 23-24/25-37/39-26 | Risk Codes | 36/37/38 |
| Molecular Structure |
|
Hazard Symbols |
 Xi
|
| Synonyms |
Hexane,tridecafluoro-1-iodo- (7CI,8CI);1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-6-iodohexane;1,1,2,2,3,3,4,4,5,5,6,6,6-Tridecafluoro-1-iodohexane;1-Iodo-1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluorohexane;1-Iodoperfluorohexane;1-Iodotridecafluorohexane;6-Iodoperfluorohexane;Perfluorohexyl iodide;Tridecafluoro-1-iodohexane;Tridecafluoro-6-iodohexane;Tridecafluorohexyl iodide;n-Perfluorohexyl iodide; |
Article Data | 24 |
Perfluoro-1-iodohexane Synthetic route
- 116-14-3
polytetrafluoroethylene
- 354-64-3
Pentafluoroethyl iodide
A
- 507-63-1
1-iodoheptadecafluorooctane
B
- 423-39-2
1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane
C
- 355-43-1
n-perfluorohexyl iodide
D
- 423-62-1
1-Iodo-perfluorodecane
| Conditions | Yield |
|---|---|
| at 100℃; for 5.13333h; Irradiation; Further byproducts given; | A 44.5% B 5% C 26.9% D 15.8% |
| at 100℃; for 5h; Irradiation; | A 13.8% B 34.6% C 40.3% D 3.2% |
| With copper at 90 - 100℃; for 5h; Product distribution; further reaction times, reagent ratio; | A 15.9% B 10.5% C 17.2% D 2.4% |
| copper at 60 - 140℃; under 22502.3 - 33753.4 Torr; Product distribution / selectivity; |
- 116-14-3
polytetrafluoroethylene
- 354-64-3
Pentafluoroethyl iodide
A
- 507-63-1
1-iodoheptadecafluorooctane
B
- 307-60-8
1-iodoperfluorododecane
C
- 355-43-1
n-perfluorohexyl iodide
D
- 423-62-1
1-Iodo-perfluorodecane
| Conditions | Yield |
|---|---|
| at 100℃; Further byproducts given; | A 44.5% B 5.8% C 26.9% D 5.8% |
| at 100℃; for 5.13333h; Irradiation; Further byproducts given; | A 44.5% B 5.8% C 26.9% D 15.8% |
| copper at 120℃; under 33753.4 Torr; Product distribution / selectivity; |
- 116-14-3
polytetrafluoroethylene
- 354-64-3
Pentafluoroethyl iodide
A
- 423-39-2
1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane
B
- 355-43-1
n-perfluorohexyl iodide
| Conditions | Yield |
|---|---|
| at 100℃; for 2h; Irradiation; | A 36.9% B 5.5% |
| at 99.9℃; under 300.02 Torr; for 0.333333h; Rate constant; Quantum yield; Thermodynamic data; Irradiation; var. of partial pressures, temp., time, Ea; | A 36.6 % Chromat. B 11.3 % Chromat. |
- 116-14-3
polytetrafluoroethylene
- 423-39-2
1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane
A
- 507-63-1
1-iodoheptadecafluorooctane
B
- 355-43-1
n-perfluorohexyl iodide
| Conditions | Yield |
|---|---|
| mit UV Licht.Irradiation; |
- 116-14-3
polytetrafluoroethylene
- 423-39-2
1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane
- 355-43-1
n-perfluorohexyl iodide
| Conditions | Yield |
|---|---|
| im UV-Licht; | |
| With bis(pentafluoropropionyl)peroxide at 28 - 70℃; for 0.333333h; Concentration; Temperature; Time; |
| Conditions | Yield |
|---|---|
| With iodine In gas at 286.9 - 426.9℃; under 30 - 300 Torr; Equilibrium constant; |
- 116-14-3
polytetrafluoroethylene
- 423-39-2
1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane
A
- 354-64-3
Pentafluoroethyl iodide
B
- 355-43-1
n-perfluorohexyl iodide
| Conditions | Yield |
|---|---|
| at 29.9℃; under 300.02 Torr; for 6h; Rate constant; Quantum yield; Thermodynamic data; Irradiation; var. of partial pressures, time, Ea; | A 70.9 % Chromat. B 5.8 % Chromat. |
- 355-43-1
n-perfluorohexyl iodide
| Conditions | Yield |
|---|---|
| With iodine |
- 116-14-3
polytetrafluoroethylene
- 2314-97-8
iodotrifluoromethane
A
- 354-64-3
Pentafluoroethyl iodide
B
- 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane
C
- 423-39-2
1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane
D
- 638-79-9
undecafluoro-1-iodopentane
E
- 355-43-1
n-perfluorohexyl iodide
F
- 335-58-0
perfluoroheptyl iodide
| Conditions | Yield |
|---|---|
| In gas Product distribution; Quantum yield; Thermodynamic data; Irradiation; pulsed CO2 laser; release of reaction enthalpy, selectivity depending on pressure and temperature; |
| Conditions | Yield |
|---|---|
| With iodine In gas at 286.9 - 426.9℃; under 30 - 300 Torr; Equilibrium constant; |
Perfluoro-1-iodohexane Chemical Properties
MF: C6F13I
MW: 445.95
BRN: 1802118
Stability: Stable.
EINECS: 206-586-6
Melting Point: -45 °C
Water Solubility: insoluble
Sensitive: Light Sensitive
Defractive index: n20/D 1.329(lit.)
Density: 2.063 g/mL at 25 °C(lit.)
Enthalpy of Vaporization: 34.07 kJ/mol
Boiling Point: 117.1 °C at 760 mmHg
Vapour Pressure: 21.1 mmHg at 25°C
Appearance: Clear very slight yellow liquidFlash Point: 45 °C
IUPAC Name: 1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-6-iodohexane
Product Categories: Organic Fluorides ; Fluorous Chemistry ; Fluorous Compounds ; Synthetic Organic Chemistry
Synonyms: 1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-6-iodohexane ; 1-Iodotridecafluorohexane ; 1-Iodoperfluorohexane ; Perfluoro-1-iodohexane ; Perfluoro-n-hexyl iodide ; Perfluorohexyl iodide ; 1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-6-iodo-hexan ; Hexane, 1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-6-iodo-
Following is the molecular structure of Perfluorohexyl iodide (355-43-1):
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Perfluoro-1-iodohexane Safety Profile
Explodes in contact with sodium when heated to the boiling point of the iodide. When heated to decomposition it emits toxic fumes of F− and I−.
Safety Information
Hazard Codes: Xi .gif){kind=small}
Risk Statements: 36/37/38
36/37/38: Irritating to eyes, respiratory system and skin
Safety Statements: 23-24/25-37/39-26
23: Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer)
24/25: Avoid contact with skin and eyes
37/39: Wear suitable gloves and eye/face protection
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
RIDADR: 2810
WGK Germany: 3
F8: Photosensitive.
Hazard Note: Irritant
HazardClass: 6.1(b)
PackingGroup: III
HS Code: 29034700
Perfluoro-1-iodohexane Specification
Handling and Storag: of Perfluorohexyl iodide (355-43-1):
Storage: Store in a cool, dry place. Do not store in direct sunlight. Store in a tightly closed container. Dark room.
Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood.
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