Ethyl (diphenylmethylsilyl)acetate

Base Information

Chemical Name:Ethyl (diphenylmethylsilyl)acetate
CAS No.:13950-57-7
Molecular Formula:C17H20 O2 Si
Molecular Weight:284.43
Hs Code.:2931900090
NSC Number:108055
DSSTox Substance ID:DTXSID80930492
Nikkaji Number:J364.743I
Wikidata:Q82905872
Mol file:13950-57-7.mol

Synonyms:Ethyl (diphenylmethylsilyl)acetate;13950-57-7;ethyl 2-[methyl(diphenyl)silyl]acetate;DTXSID80930492;MFIAJOGCRUYZQO-UHFFFAOYSA-N;Ethyl [methyl(diphenyl)silyl]acetate;NSC108055;Ethyl [methyl(diphenyl)silyl]acetate #;NSC-108055

Suppliers and Price of Ethyl (diphenylmethylsilyl)acetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of Ethyl (diphenylmethylsilyl)acetate

Chemical Property:

Vapor Pressure:3.84E-05mmHg at 25°C
Boiling Point:352.4°Cat760mmHg
Flash Point:142.8°C
PSA：26.30000
Density:1.04g/cm³
LogP:2.44250
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:6
Exact Mass:284.123256411
Heavy Atom Count:20
Complexity:286

Purity/Quality:: 97% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOC(=O)C[Si](C)(C1=CC=CC=C1)C2=CC=CC=C2
Physical properties clear to light yellow liquids.
Uses vinyl 1,1-dication synthetic equivalent in reactions with Grignard reagents; reagent for Peterson synthesis of α,β-un saturated esters.

Technology Process of Ethyl (diphenylmethylsilyl)acetate

There total 5 articles about Ethyl (diphenylmethylsilyl)acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 144-79-6
chloromethyldiphenylsilane

: 141-78-6
ethyl acetate

: 13950-57-7
ethyl α-(diphenylmethylsilyl)acetate

Guidance literature:: With lithium diisopropyl amide; In tetrahydrofuran; hexane; 1.) -78 deg C, 40 min, 2.) -78 deg C, 1 h, room temperature;