Selenocyanic acid, 3-chlorophenyl ester

Base Information

• Chemical Name: Selenocyanic acid, 3-chlorophenyl ester
• CAS No.: 32111-96-9
• Molecular Formula: C7H4ClNSe
• Molecular Weight: 216.528
• Mol file: 32111-96-9.mol

Synonyms:

Chemical Property of Selenocyanic acid, 3-chlorophenyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Selenocyanic acid, 3-chlorophenyl ester

There total 4 articles about Selenocyanic acid, 3-chlorophenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

trimethylsilyl cyanide (7677-24-9) + 3-chlorophenylboronic acid (63503-60-6) → 1-chloro-3-selenocyanatobenzene (32111-96-9)

Guidance literature:

With selenium; In dimethyl sulfoxide; at 120 ℃; Schlenk technique; Green chemistry;

DOI:10.1002/chem.202004005

Reference yield: 81.0%

→ 1-chloro-3-selenocyanatobenzene (32111-96-9)

Guidance literature:

With selenium; In dimethyl sulfoxide; at 120 ℃; for 24h; Schlenk technique;

Reference yield:

potassium selenocyanate (3425-46-5) + 3-chloro-aniline (108-42-9) → 1-chloro-3-selenocyanatobenzene (32111-96-9)

Guidance literature:

3-chloro-aniline; With sulfuric acid; sodium nitrite; at 20 ℃;

potassium selenocyanate; at 20 ℃;

DOI:10.1002/ejic.201000607

upstream raw materials:

potassium selenocyanate

3-chloro-aniline

trimethylsilyl cyanide

3-chlorophenylboronic acid

Downstream raw materials:

(3-chloro-phenyl)-(4-chloro-phenyl)-selenide

(4-bromo-phenyl)-(3-chloro-phenyl)-selenide

biphenyl-4-yl-(3-chloro-phenyl)-selenide

(3-chlorophenyl)(phenyl)selane

Refernces

• 1、 -. "Preparation method of arylselenocyanate compound". Paragraph 0021-0022; 0027-0028; 0057-0059. . Retrieved 2020/12/29.
• 2、 Makarov, Arkady G.,Bagryanskaya, Irina Yu.,Gatilov, Yuri V.,Kuratieva, Natalia V.,Makarov, Alexander Yu.,Shakirov, Makhmut M.,Alexeyev, Alexey V.,Tersago, Karla,Van Alsenoy, Christian,Blockhuys, Frank,Zibarev, Andrey V.. "The first observation of the E,Z configuration of Ar-X-N=S=N-X-Ar (X = S, Se) chains in the crystalline state". scheme or table. p. 4801 - 4810. Retrieved 2011/03/01.