2,5-Dinitro-9h-fluoren-9-one

Base Information

• Chemical Name: 2,5-Dinitro-9h-fluoren-9-one
• CAS No.: 53197-58-3
• Molecular Formula: C13H6N2O5
• Molecular Weight: 270.201
• Hs Code.: 2914700090
• European Community (EC) Number: 668-164-1
• NSC Number: 12366
• DSSTox Substance ID: DTXSID80279338
• Nikkaji Number: J308.206G
• Wikidata: Q82011849
• Mol file: 53197-58-3.mol

Synonyms:2,5-dinitro-9h-fluoren-9-one;2,5-dinitrofluoren-9-one;53197-58-3;2,5-Dinitrofluorenon;NSC12366;SCHEMBL8100705;DTXSID80279338;2,5-DINITRO-9-FLUORENONE;NSC 12366;NSC-12366;AKOS015997038

Chemical Property of 2,5-Dinitro-9h-fluoren-9-one

Chemical Property:

• Vapor Pressure: 2.71E-10mmHg at 25°C
• Melting Point: 241 °C
• Boiling Point: 504.2°C at 760 mmHg
• Flash Point: 263.5°C
• PSA: 108.71000
• Density: 1.603g/cm³
• LogP: 3.76080
• XLogP3: 2.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 0
• Exact Mass: 270.02767130
• Heavy Atom Count: 20
• Complexity: 455

Purity/Quality:

98%,99%, ^*data from raw suppliers

2,5-DINITRO-9-FLUORENONE Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC2=C(C3=C(C2=O)C=C(C=C3)[N+](=O)[O-])C(=C1)[N+](=O)[O-]

Technology Process of 2,5-Dinitro-9h-fluoren-9-one

There total 2 articles about 2,5-Dinitro-9h-fluoren-9-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

9-fluorenone (486-25-9,952573-42-1) → 2,7-dinitro-9-fluorenone (31551-45-8) + 2-nitro-9H-fluoren-9-one (3096-52-4) + 2,5-dinitrofluorenone (53197-58-3) + 3-nitro-9H-fluoren-9-one (42135-22-8) + 1,8-dinitro-fluoren-9-one (116365-50-5)

Guidance literature:

With ammonium cerium(IV) nitrate; In acetic acid; Mechanism; Heating;

Reference yield:

9-fluorenone (486-25-9,952573-42-1) → 2,7-dinitro-9-fluorenone (31551-45-8) + 2,5-dinitrofluorenone (53197-58-3)

Guidance literature:

With nitric acid;

Reference yield:

2,5-dinitrofluorenone (53197-58-3) + 4-fluoroaniline (371-40-4) → (2,5-dinitro-fluoren-9-ylidene)-(4-fluoro-phenyl)-amine (387-01-9)

Guidance literature:

With zinc(II) chloride;

DOI:10.1021/jo01111a010

upstream raw materials:

9-fluorenone

Downstream raw materials:

2,5-Diamino-9H-fluoren-9-one

(2,5-dinitro-fluoren-9-ylidene)-phenyl-amine

(2,5-dinitro-fluoren-9-ylidene)-(4-fluoro-phenyl)-amine

2,5-Dihydroxy-9H-fluoren-9-on