1-Chloro-1-phenylsiletane

Base Information

• Chemical Name: 1-Chloro-1-phenylsiletane
• CAS No.: 3401-28-3
• Molecular Formula: C9H11ClSi
• Molecular Weight: 182.725
• DSSTox Substance ID: DTXSID00503900
• Wikidata: Q82358006
• Mol file: 3401-28-3.mol

Synonyms:1-Chloro-1-phenylsiletane;3401-28-3;1-phenyl-1-chloro-1-silacyclobutane;Silacyclobutane, 1-chloro-1-phenyl-;SCHEMBL5034205;DTXSID00503900;DBYRASAQTCQQMB-UHFFFAOYSA-N;1-chloro-1-phenyl-1-silacyclobutane

Chemical Property of 1-Chloro-1-phenylsiletane

Chemical Property:

• PSA: 0.00000
• LogP: 2.48160
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 182.0318546
• Heavy Atom Count: 11
• Complexity: 137

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1C[Si](C1)(C2=CC=CC=C2)Cl

Technology Process of 1-Chloro-1-phenylsiletane

There total 9 articles about 1-Chloro-1-phenylsiletane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

1,3-Dichloropropane (142-28-9) + chlorobenzene (108-90-7) → 1-chloro-1-phenyl-1-silacyclobutane (3401-28-3)

Guidance literature:

chlorobenzene; With n-butyllithium; tetrachlorosilane; In tetrahydrofuran; hexane; at -50 - 25 ℃; for 4h;

1,3-Dichloropropane; With magnesium; In tetrahydrofuran; hexane; at -20 - 50 ℃; for 2h; Time;

Reference yield: 85.0%

1,3-Dichloropropane (142-28-9) + Phenyltrichlorosilane (98-13-5) → 1-chloro-1-phenyl-1-silacyclobutane (3401-28-3)

Guidance literature:

1,3-Dichloropropane; With magnesium; In tetrahydrofuran; at -50 - -20 ℃; for 2h;

Phenyltrichlorosilane; In tetrahydrofuran; at -40 - 60 ℃; for 3h;

Reference yield: 85.0%

Phenyltrichlorosilane (98-13-5) + 1,3-dibromo-propane (109-64-8) → 1-chloro-1-phenyl-1-silacyclobutane (3401-28-3)

Guidance literature:

1,3-dibromo-propane; With magnesium; In tetrahydrofuran;

Phenyltrichlorosilane; In tetrahydrofuran; at -20 - 50 ℃; for 2h;

upstream raw materials:

1,1-dichlorosilacyclobutane

phenylmagnesium bromide

1,3-Dichloropropane

chlorobenzene

Downstream raw materials:

1-allyloxy-1-phenylsilacyclobutane

1-((Z)-1-Ethyl-propenyloxy)-1-phenyl-siletane

1-phenyl-1-vinyl-1-silacyclobutane

1-(Cyclohex-1-enyloxy)-1-phenyl-siletane