Trichloro[bis(trifluoromethyl)]-lambda~5~-phosphane

Base Information

• Chemical Name: Trichloro[bis(trifluoromethyl)]-lambda~5~-phosphane
• CAS No.: 353-77-5
• Molecular Formula: C2Cl3F6P
• Molecular Weight: 275.345
• DSSTox Substance ID: DTXSID00559740
• Wikidata: Q82442574
• Mol file: 353-77-5.mol

Synonyms:Trichloro[bis(trifluoromethyl)]-lambda~5~-phosphane;353-77-5;SCHEMBL5622699;DTXSID00559740;PEPIQGCIUVDGLO-UHFFFAOYSA-N;trichlorobis(trifluoromethyl)phosphorane

Chemical Property of Trichloro[bis(trifluoromethyl)]-lambda~5~-phosphane

Chemical Property:

• XLogP3: 4.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 0
• Exact Mass: 273.870739
• Heavy Atom Count: 12
• Complexity: 166

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(F)(F)(F)P(C(F)(F)F)(Cl)(Cl)Cl

Technology Process of Trichloro[bis(trifluoromethyl)]-lambda~5~-phosphane

There total 3 articles about Trichloro[bis(trifluoromethyl)]-lambda~5~-phosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 25.0%

(difluorothiophosphoryl)thio-bis(trifluoromethyl)phosphine (52226-01-4) → thiophosphoryl chloride difluoroide (2524-02-9) + (S2PF2)2 (15538-60-0) + bis(trifluoromethyl)chlorophosphine (650-52-2) + bis(trifluoromethyl)trichlorophosphorane (353-77-5)

Guidance literature:

With chlorine; at room temp.;

Reference yield:

{bis(trifluoromethyl)thiophosphoryl}thio-bis(trifluoromethyl)phosphine (23526-69-4) → disulfur dichloride (10025-67-9) + bis(trifluoromethyl)trichlorophosphorane (353-77-5) + Bis(trifluormethyl)-thiophosphinsaeurechlorid (18799-82-1)

Guidance literature:

With chlorine; warming from -45°C to 20°C within 24 h;

DOI:10.1021/ja00739a004

Reference yield:

amino-bis-trifluoromethyl-phosphine (431-95-8) → (CF3)2PNH2*Cl2 + chlorotrifluoromethane (75-72-9) + bis(trifluoromethyl)trichlorophosphorane (353-77-5)

Guidance literature:

With chlorine; byproducts: NH4Cl; 20°C;

DOI:10.1039/JR9580000512

upstream raw materials:

amino-bis-trifluoromethyl-phosphine

{bis(trifluoromethyl)thiophosphoryl}thio-bis(trifluoromethyl)phosphine

(difluorothiophosphoryl)thio-bis(trifluoromethyl)phosphine

Downstream raw materials:

trifluoromethan

Bis-(trifluoromethyl)-chlorophosphazodiphenylphosphazobis-(heptafluoropropyl)-phosphin