Sulfur monochloride

Base Information

• Chemical Name: Sulfur monochloride
• CAS No.: 10025-67-9
• Molecular Formula: Cl2S2
• Molecular Weight: 135.038
• Hs Code.: 2812.10
• European Community (EC) Number: 233-036-2
• ICSC Number: 0958
• UN Number: 1828
• UNII: NJ7YR2EV0D
• DSSTox Substance ID: DTXSID3042427
• Nikkaji Number: J98.297K
• Wikipedia: Disulfur dichloride,Disulfur_dichloride
• Wikidata: Q414657
• Mol file: 10025-67-9.mol

Synonyms:sulfur chloride;sulfur monochloride

Chemical Property of Sulfur monochloride

Chemical Property:

• Appearance/Colour: Light amber to yellowish red oily liquid with choking and irritant stench
• Vapor Pressure: 6.8 mm Hg ( 20 °C)
• Melting Point: -80 °C(lit.)
• Refractive Index: n20/D 1.658(lit.)
• Boiling Point: 137.999 °C at 760 mmHg
• Flash Point: 118ºC
• PSA: 50.60000
• Density: 1.704 g/cm³
• LogP: 2.67540
• Storage Temp.: Store below +30°C.
• Water Solubility.: reacts
• XLogP3: 2.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 133.8818477
• Heavy Atom Count: 4
• Complexity: 6
• Transport DOT Label: Corrosive

Purity/Quality:

99.9% ^*data from raw suppliers

Sulfur monochloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T,C,N
• Hazard Codes: T,C,N
• Statements: 14-20-25-29-35-50-67-40-37-22
• Safety Statements: 26-36/37/39-45-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Toxic Gases & Vapors -> Other Toxic Gases & Vapors
• Canonical SMILES: S(SCl)Cl
• Inhalation Risk: A harmful contamination of the air can be reached very quickly on evaporation of this substance at 20 °C.
• Effects of Short Term Exposure: Lachrymation. The substance is corrosive to the eyes, skin and respiratory tract. Corrosive on ingestion. Inhalation of the vapour may cause lung oedema. The effects may be delayed. Medical observation is indicated.
• Physical Properties: Yellowish red oily liquid; pungent penetrating odor; fumes in air; refractive index 1.670 at 20°C; dipole moment 1.60; dielectric constant 4.9 at 22°C; reacts with water; soluble in ethanol, benzene, ether, chloroform, and carbon tetrachloride: dissolves sulfur at ambient temperature (67 g/100 g sulfur chloride).
• Uses: Sulfur chloride is a solvent for sulfur and a chlorinating agent. Other applications are vulcanizing rubber; an intermediate in making sulfur dyes, synthetic rubber, thionyl chloride, and several other compounds; pesticide formulations; hardening soft woods; and extracting gold. Disulfur dichloride is used as Intermediate and chlorinating agent in the manufacture of organic chemicals, sulfur dyes, insecticides, synthetic rubbers; in cold vulcanization of rubber; as polymerization catalyst for vegetable oils; for hardening soft woods. The chemical fiber industry is used as a finishing agent for the manufacture of fabrics. The metallurgical industry is used as an extraction agent for precious and rare metals such as gold and silver.

Technology Process of Sulfur monochloride

There total 188 articles about Sulfur monochloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ disulfur dichloride (10025-67-9)

Guidance literature:

Reference yield:

→ disulfur dichloride (10025-67-9) + 2,5-dichloro-thiazolo[4,5-d]thiazole (59820-69-8)

Guidance literature:

Reference yield:

arsenic trisulfide + chlorine (7782-50-5) → disulfur dichloride (10025-67-9)

Guidance literature:

In not given; room temp.;;

upstream raw materials:

chlorine

sulfur

potassium chlorate

sulfur dioxide

Downstream raw materials:

sulfur dicyanide

sulfur dirhodanide

iron(III) chloride

aluminium trichloride

Refernces

• 1、 Booth, H. S.,Mericola, F. C.. "". . p. 640 - 642. Retrieved 1940.
• 2、 Rauch,DiSalvo,Zhou,Tang,Edwards. "Synthesis and structure of W3S4Cl4". . p. 253 - 264. Retrieved 1992.
• 3、 Lenher, V.. "". . p. 29 - 35. Retrieved 1921.
• 4、 North, H. B.,Thomson, J. C.. "". . p. 774 - 777. Retrieved 1918.
• 5、 North, H. B.. "". . p. 184 - 187. Retrieved 1910.
• 6、 Evans, A. G.,Meadows, G. W.. "". . p. 667 - 674. Retrieved 1947.
• 7、 Veena, S.,Padma, D. K.. "A gravimetric procedure for determination of sulphur in disulphur dichloride". . p. 414. Retrieved 2007/10/02.