3-chloro-3-methyl-3H-diazirene

Base Information

• Chemical Name: 3-chloro-3-methyl-3H-diazirene
• CAS No.: 4222-21-3
• Molecular Formula: C2H3ClN2
• Molecular Weight: 90.5122
• Mol file: 4222-21-3.mol

Synonyms:

Chemical Property of 3-chloro-3-methyl-3H-diazirene

Chemical Property:

• Vapor Pressure: 358mmHg at 25°C
• Boiling Point: 45.8°C at 760 mmHg
• Density: 1.54g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3-chloro-3-methyl-3H-diazirene

There total 1 articles about 3-chloro-3-methyl-3H-diazirene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

acetamidine hydrochloride (124-42-5) → methylchlorodiazirine (4222-21-3)

Guidance literature:

acetamidine hydrochloride; With lithium chloride; In dimethyl sulfoxide; at 0 ℃; for 0.333333h;

With sodium hypochlorite; sodium chloride; In dimethyl sulfoxide; at 0 ℃; for 0.5h; Further stages.;

DOI:10.1021/ja071799i

Reference yield: 90.0%

methylchlorodiazirine (4222-21-3) → chloroethylene (75-01-4,9002-86-2)

Guidance literature:

In n-heptane; Quantum yield; Irradiation;

DOI:10.1016/S0040-4039(00)97817-1

Reference yield: 19.0%

methyl 2-hydroxycinnamate (6236-69-7) + methylchlorodiazirine (4222-21-3) → methyl 2-methoxycinnamate (98288-15-4) + methyl 1a,6b-dihydro-c-1a-methylcyclopropabenzofuran-r-1-carboxylate

Guidance literature:

With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; sodium ethanolate; In tetrahydrofuran; ethanol; a) -15 deg C, 3.5 h, b) r.t., 2 d;

DOI:10.1002/hlca.19930760114

upstream raw materials:

acetamidine hydrochloride

Downstream raw materials:

chloroethylene

C₇H₈ClN

1-chloro-1,2,2,3,3-pentamethylcyclopropane

methyl 2-methoxycinnamate