(z)-(1-Methyl-2-propenyl)cyclohexane

Base Information

• Chemical Name: (z)-(1-Methyl-2-propenyl)cyclohexane
• CAS No.: 3645-01-0
• Molecular Formula: C10H18
• Molecular Weight: 138.253
• DSSTox Substance ID: DTXSID101294978
• Nikkaji Number: J514.897I
• Mol file: 3645-01-0.mol

Synonyms:3645-01-0;DTXSID101294978;(1-Methyl-2-propen-1-yl)cyclohexane;(z)-(1-methyl-2-propenyl)cyclohexane

Chemical Property of (z)-(1-Methyl-2-propenyl)cyclohexane

Chemical Property:

• XLogP3: 4.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 138.140850574
• Heavy Atom Count: 10
• Complexity: 98.6

Purity/Quality:

99% ,98%,Electron Grade , ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC(C=C)C1CCCCC1

Technology Process of (z)-(1-Methyl-2-propenyl)cyclohexane

There total 11 articles about (z)-(1-Methyl-2-propenyl)cyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

methyl magnesium iodide (917-64-6) + (E)-3-cyclohexyl-2-propen-1-ol (42134-55-4,132350-24-4,114096-03-6) → 3-cyclohexyl-1-butene (3645-01-0)

Guidance literature:

(E)-3-cyclohexyl-2-propen-1-ol; With dmap; 1′-(diphenylphosphino)ferrocene-1-carboxylic acid; dicyclohexyl-carbodiimide; In dichloromethane; at 24 ℃; for 48h;

methyl magnesium iodide; With copper(I) bromide dimethylsulfide complex; In diethyl ether; at 24 ℃; for 2h;

DOI:10.1055/s-2004-831247

Reference yield: 62.0%

fluorocyclohexane (372-46-3) + vinylmagnesium chloride (3536-96-7) → 3-cyclohexyl-1-butene (3645-01-0)

Guidance literature:

With bis(triphenylphosphine)nickel(II) chloride; In tetrahydrofuran; at 25 ℃; for 20h;

DOI:10.1021/ja042565r

Reference yield:

but-2t-enyl-dimethyl-sulfonium; bromide + cyclohexylmagnesium bromide (931-50-0) → 3-cyclohexyl-1-butene (3645-01-0)

Guidance literature:

With copper(I) bromide; In tetrahydrofuran; at -30 - 0 ℃; for 1h;

DOI:10.1016/S0022-328X(00)91810-2

upstream raw materials:

cyclohexylmagnesium bromide

3-chloro-1-iodo-1-propyne

bis(cyclohexanyl)borane

methyllithium