10-Oxoundecanoic acid ethyl ester

Base Information

• Chemical Name: 10-Oxoundecanoic acid ethyl ester
• CAS No.: 36651-38-4
• Molecular Formula: C₁₃H₂₄O₃
• Molecular Weight: 228.332
• Mol file: 36651-38-4.mol

Synonyms:Undecanoic acid,10-oxo-,ethyl ester;10-Oxoundekancarbonsaeureethylester;ethyl 10-oxo-decanecarboxylate;10-oxo-undecanoic acid ethyl ester;10-Oxo-undecansaeure-aethylester;

Chemical Property of 10-Oxoundecanoic acid ethyl ester

Chemical Property:

• Melting Point: 112.5-113.6 °C
• Boiling Point: 169-170 °C(Press: 12 Torr)
• PSA: 43.37000
• Density: 0.936±0.06 g/cm3(Predicted)
• LogP: 3.25930

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 10-Oxoundecanoic acid ethyl ester

There total 9 articles about 10-Oxoundecanoic acid ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

ethyl 10-undecenenoate (692-86-4) → ethyl 10-oxo-decanecarboxylate (36651-38-4)

Guidance literature:

With oxygen; copper dichloride; palladium dichloride; In water; N,N-dimethyl-formamide; for 20h;

DOI:10.1021/tx9501602

Reference yield: 60.0%

ethanol (64-17-5) + ethyl 9-(oxiran-2-yl)nonanoate (105462-90-6) → ethyl 10-oxo-decanecarboxylate (36651-38-4) + Diethyl 3-hydroxydodecanedioate (106185-72-2)

Guidance literature:

With potassium carbonate; dicobalt octacarbonyl; at 40 ℃; for 72h; Yield given;

DOI:10.1055/s-1986-31686

Reference yield:

9-ethoxycarbonylnonanoic acid chloride (6946-46-9) + dimethylcadmium (506-82-1) → ethyl 10-oxo-decanecarboxylate (36651-38-4)

Guidance literature:

With benzene;

DOI:10.1021/ja01214a061

upstream raw materials:

9-ethoxycarbonylnonanoic acid chloride

dimethylcadmium

methylzinc iodide

methylaluminum dichloride

Downstream raw materials:

10-oxo-undecanoic acid

Aethyl-10-hydroxy-10-(1'-phenylthiocycloprop-1'-yl)undecanoat

4-(11-azidoundecyl-2-amino)quinazoline

(2S,5R,6R)-12-(5-hydroxy-6-methyl-piperidin-2-yl)-dodecan-2-one