Methylaluminium dichloride

Base Information

• Chemical Name: Methylaluminium dichloride
• CAS No.: 917-65-7
• Molecular Formula: CH3AlCl2
• Molecular Weight: 112.922
• European Community (EC) Number: 213-032-7
• DSSTox Substance ID: DTXSID301312386
• Mol file: 917-65-7.mol

Synonyms:Methylaluminium dichloride;917-65-7;Aluminum methyl dichloride;dichloro(methyl)alumane;Aluminum, dichloromethyl-;EINECS 213-032-7;CH3AlCl2;Aluminium, dichloromethyl-;C-H3-Al-Cl2;DTXSID301312386;AKOS015915464;FT-0652313

Chemical Property of Methylaluminium dichloride

Chemical Property:

• Melting Point: 72.7℃ [CRC10]
• Boiling Point: 95℃ [CRC10]
• Flash Point: −9 °F
• PSA: 0.00000
• Density: 0.729 g/mL at 25 °C
• LogP: 1.96280
• Water Solubility.: Soluble bz, eth, hydrocarbon solvents [CRC10]
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 111.9427189
• Heavy Atom Count: 4
• Complexity: 13.5

Purity/Quality:

99% ^*data from raw suppliers

ALUMINUM METHYL DICHLORIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F;C
• Hazard Codes: F,C,N
• Statements: 11-14-34-48/20-51/53-62-65-67-14/15
• Safety Statements: 16-26-36/37/39-43-45-62-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C[Al](Cl)Cl

Technology Process of Methylaluminium dichloride

There total 18 articles about Methylaluminium dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methylene chloride (74-87-3) → methylaluminum dichloride (917-65-7) + dimethylaluminum chloride (1184-58-3)

Guidance literature:

With aluminium trichloride; bei Ausschluss von Feuchtigkeit und Sauerstoff;

DOI:10.1021/ja01276a504

Reference yield:

methylene chloride (74-87-3) → methylaluminum dichloride (917-65-7) + dimethylaluminum chloride (1184-58-3)

Guidance literature:

With aluminium trichloride; bei Ausschluss von Feuchtigkeit und Sauerstoff;

DOI:10.1021/ja01276a504

Reference yield:

methylene chloride (74-87-3) → methylaluminum dichloride (917-65-7) + dimethylaluminum chloride (1184-58-3)

Guidance literature:

DOI:10.1021/ja01276a504

upstream raw materials:

methylene chloride

chloroform

aluminium trichloride

iodine

Downstream raw materials:

ethyl 10-oxo-decanecarboxylate

trimethylaluminum

methylmercury(II) chloride

methylmercury(II) iodide

Refernces

• 1、 Schumann, Herbert. "Intramolecularly sulfur stabilized aluminum and gallium alkyl derivatives". . p. 1828 - 1835. Retrieved 2001.
• 2、 -. "PROCESS FOR THE PREPARATION OF METHYLALUMINIUM DICHLORIDE". Page/Page column 6. . Retrieved 2008/06/13.