Dodecanedioic acid, 3-hydroxy-, diethyl ester

Base Information

• Chemical Name: Dodecanedioic acid, 3-hydroxy-, diethyl ester
• CAS No.: 106185-72-2
• Molecular Formula: C16H30O5
• Molecular Weight: 302.411
• Mol file: 106185-72-2.mol

Synonyms:

Chemical Property of Dodecanedioic acid, 3-hydroxy-, diethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Dodecanedioic acid, 3-hydroxy-, diethyl ester

There total 1 articles about Dodecanedioic acid, 3-hydroxy-, diethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

ethanol (64-17-5) + ethyl 9-(oxiran-2-yl)nonanoate (105462-90-6) → ethyl 10-oxo-decanecarboxylate (36651-38-4) + Diethyl 3-hydroxydodecanedioate (106185-72-2)

Guidance literature:

With potassium carbonate; dicobalt octacarbonyl; at 40 ℃; for 72h; Yield given;

DOI:10.1055/s-1986-31686

Reference yield:

methanol (67-56-1) + Diethyl 3-hydroxydodecanedioate (106185-72-2) → 2-(6-methoxycarbonylhexyl)cyclopent-2-en-1-one (34546-57-1) + methyl ester of 2-(5-carboxypentyl)cyclohex-2-en-1-one (100853-02-9)

Guidance literature:

With hydrogenchloride; PPA; Yield given. Multistep reaction. Yields of byproduct given; 1.) 100 deg C, 1 h, 2.) room temp., 1 d;

DOI:10.1055/s-1986-31686

upstream raw materials:

ethanol

ethyl 9-(oxiran-2-yl)nonanoate

Downstream raw materials:

2-(6-methoxycarbonylhexyl)cyclopent-2-en-1-one

methyl ester of 2-(5-carboxypentyl)cyclohex-2-en-1-one