Phenanthrene, 9-(4-methoxyphenyl)-

Base Information

• Chemical Name: Phenanthrene, 9-(4-methoxyphenyl)-
• CAS No.: 37842-67-4
• Molecular Formula: C21H16O
• Molecular Weight: 284.357
• Mol file: 37842-67-4.mol

Synonyms:

Chemical Property of Phenanthrene, 9-(4-methoxyphenyl)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Phenanthrene, 9-(4-methoxyphenyl)-

There total 23 articles about Phenanthrene, 9-(4-methoxyphenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

2-((4-methoxyphenyl)ethynyl)-1,1′-biphenyl (725213-45-6) → 10-(4-methoxyphenyl)phenanthrene (37842-67-4)

Guidance literature:

With copper(II) bis(trifluoromethanesulfonate); eosin y; In dichloromethane; at 20 ℃; for 72h; Solvent; Reagent/catalyst; Wavelength; Catalytic behavior; Sealed tube; Irradiation; Inert atmosphere;

DOI:10.1039/c6cc03725a

Reference yield: 98.0%

phenanthren-9-yl 4-methylbenzenesulfonate + 4-methoxyphenylmagnesium chloride (699-19-4) → 10-(4-methoxyphenyl)phenanthrene (37842-67-4)

Guidance literature:

With cobalt (III) fluoride; N,N′-bis(2,6-diisopropylphenyl)imidazol-2-ylidene hydrochloride; In tetrahydrofuran; at 80 ℃; for 5h;

DOI:10.1002/cctc.202001347

Reference yield: 70.0%

phenanthrene (85-01-8) + para-iodoanisole (696-62-8) → 10-(4-methoxyphenyl)phenanthrene (37842-67-4)

Guidance literature:

With palladium diacetate; silver carbonate; trifluoroacetic acid; at 80 ℃; for 12h;

DOI:10.1039/c7cy01040k

upstream raw materials:

1-biphenyl-2-yl-2-methoxy-ethanone

4-methoxyphenyl magnesium bromide

4-(9-phenanthryl)phenol

dimethyl sulfate

Downstream raw materials:

4-(9-phenanthryl)phenol