CID 10996957

Base Information

• Chemical Name: CID 10996957
• CAS No.: 20762-60-1
• Molecular Formula: KN3
• Molecular Weight: 81.1184
• Nikkaji Number: J38.341D
• Mol file: 20762-60-1.mol

Synonyms:

Chemical Property of CID 10996957

Chemical Property:

• Melting Point: 350oC
• PSA: 49.75000
• Density: 2.040
• LogP: 0.21376
• Water Solubility.: g/100g H2O: 41.4 (0°C), 50.8 (20°C), 61.0 (40°C), 106 (100°C) [LAN05]
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 80.97292850
• Heavy Atom Count: 4
• Complexity: 26.3

Purity/Quality:

98%,99%, ^*data from raw suppliers

Potassium azide ≥99.9% trace metals basis ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T
• Hazard Codes: T
• Statements: 25
• Safety Statements: 45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [N-]=[N+]=[N-].[K+]

Technology Process of CID 10996957

There total 23 articles about CID 10996957 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

potassium amide + dinitrogen monoxide (10024-97-2) → potassium azide (20762-60-1)

Guidance literature:

byproducts: KOH, NH3; 270-280 °C in rotating furnace; the white layer of KOH and KN3 dissolved in water, the soln. evaporated, KN3 crystd.;

Reference yield: 90.0%

potassium hexamethylsilazane (40949-94-8) + dinitrogen monoxide (10024-97-2) → potassium azide (20762-60-1)

Guidance literature:

In tetrahydrofuran; at 20 ℃; under 760.051 Torr;

DOI:10.1021/acs.inorgchem.8b02129

Reference yield: 80.0%

lead(II) nitrate + potassium amide → potassium azide (20762-60-1)

Guidance literature:

In ammonia; heating at 90 °C in closed tube;

upstream raw materials:

potassium

potassium carbonate

hydrogen azide

nitrogen

Downstream raw materials:

nitrogen

hydrogen

potassium

cyanogen azide

Refernces

• 1、 Pfeiffer, Steffen,Nuss, Juergen,Jansen, Martin. "The chain manganates K29Mn17O34, Rb 11Mn8O16, and Cs4Mn 3O6: a new family of mixed-valent one-dimensional transition metallates". . p. 23 - 29. Retrieved 2010.
• 2、 Nuss, Jürgen,Dasari, Prasad L. V. K.,Jansen, Martin. "K5Mn3O6and Rb8Mn5O10, new charge ordered quasi one-dimensional oxomanganates (II, III)". . p. 316 - 321. Retrieved 2015.
• 3、 Gunka, Piotr A.,Kraszewski, Karol,Chen, Yu-Sheng,Zachara, Janusz. "The structure and energetics of arsenic(iii) oxide intercalated by ionic azides". . p. 12776 - 12783. Retrieved 2014.
• 4、 Liu, Yizhu,Eymann, Léonard Y. M.,Solari, Euro,Fadaei Tirani, Farzaneh,Scopelliti, Rosario,Severin, Kay. "Trimethylsilyl-Induced N-O Bond Cleavage in Nitrous Oxide-Derived Aminodiazotates". supporting information. p. 11859 - 11863. Retrieved 2018/09/25.