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20762-60-1

Basic Information
CAS No.: 20762-60-1
Name: potassium azide
Article Data: 43
Molecular Structure:
Molecular Structure of 20762-60-1 (potassium azide)
Formula: KN3
Molecular Weight: 81.1184
Synonyms: Potassiumazide (6CI,8CI); PPG 101
EINECS: 244-013-1
Density: 2.040
Melting Point: 350oC
Solubility: g/100g H2O: 41.4 (0°C), 50.8 (20°C), 61.0 (40°C), 106 (100°C) [LAN05]
Hazard Symbols: T
Risk Codes: 25
Safety: A poison by ingestion. Hydrolysis yields KOH which is toxic and irritating. When heated it explodes weakly releasing nitrogen. Explosive reaction with sulfur dioxide at 120°C. Reacts with carbon disulfide to form an explosive product. Reacts violently with manganese dioxide when warmed. When heated to decomposition it emits very toxic fumes of NOx and K2O. See also AZIDES.
PSA: 49.75000
LogP: 0.21376
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Chemistry

Molecular Structure:

Molecular Formula: KN3
Molecular Weight: 81.1184
IUPAC Name: Potassium Azide
Synonyms of Potassium Azide (CAS NO.20762-60-1): AI3-52879 ; Caswell No. 682B ; EINECS 244-013-1 ; EPA Pesticide Chemical Code 107702 ; Potassium azide (K(N3))
CAS NO: 20762-60-1

Uses

  Potassium Azide (CAS NO.20762-60-1) has been found to act as a nitrification inhibitor in soil.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
bird - wild LD50 oral 17800ug/kg (17.8mg/kg)   Archives of Environmental Contamination and Toxicology. Vol. 12, Pg. 355, 1983.
rat LD50 oral 27mg/kg (27mg/kg)   National Technical Information Service. Vol. PB85-143766,

Safety Profile

A poison by ingestion. Hydrolysis yields KOH which is toxic and irritating. When heated it explodes weakly releasing nitrogen. Explosive reaction with sulfur dioxide at 120°C. Reacts with carbon disulfide to form an explosive product. Reacts violently with manganese dioxide when warmed. When heated to decomposition it emits very toxic fumes of NOx and K2O. See also AZIDES
RIDADR of Potassium Azide (CAS NO.20762-60-1): 2811
HazardClass: 6.1(a)
PackingGroup: II

Specification

  Potassium Azide (CAS NO.20762-60-1) is a colorless crystals. It is a salt of hydrazoic acid, and crystallizes in a tetragonal structure. Upon heating or irradiation with ultraviolet light, it decomposes into potassium metal and nitrogen gas. Unlike heavy-metal azides, it is not sensitive to shock, but may explode if heated rapidly.