2-Pyridinamine, N,N'-[5'-[4-(di-2-pyridinylamino)phenyl][1,1':3',1''-terphenyl]-4,4''-diyl]bis[ N-2-pyridinyl-

Base Information

• Chemical Name: 2-Pyridinamine, N,N'-[5'-[4-(di-2-pyridinylamino)phenyl][1,1':3',1''-terphenyl]-4,4''-diyl]bis[ N-2-pyridinyl-
• CAS No.: 391594-50-6
• Molecular Formula: C54H39N9
• Molecular Weight: 813.964
• Mol file: 391594-50-6.mol

Synonyms:

Chemical Property of 2-Pyridinamine, N,N'-[5'-[4-(di-2-pyridinylamino)phenyl][1,1':3',1''-terphenyl]-4,4''-diyl]bis[ N-2-pyridinyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-Pyridinamine, N,N'-[5'-[4-(di-2-pyridinylamino)phenyl][1,1':3',1''-terphenyl]-4,4''-diyl]bis[ N-2-pyridinyl-

There total 2 articles about 2-Pyridinamine, N,N'-[5'-[4-(di-2-pyridinylamino)phenyl][1,1':3',1''-terphenyl]-4,4''-diyl]bis[ N-2-pyridinyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

di(pyridin-2-yl)amine (1202-34-2) + 1,3,5-tris(4-bromophenyl)benzene (7511-49-1) → 2,4,6-tris[p-(2,2'-dipyridylamino)phenyl]-benzene (391594-50-6)

Guidance literature:

With potassium carbonate; copper(II) sulfate; at 210 ℃; for 8h;

DOI:10.1002/1521-3773(20011105)40

Reference yield:

para-bromoacetophenone (99-90-1) → 2,4,6-tris[p-(2,2'-dipyridylamino)phenyl]-benzene (391594-50-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 82 percent / SiCl₄ / ethanol / 25 h / 0 - 20 °C

2: 85 percent / K₂CO₃; CuSO₄ / 8 h / 210 °C

With tetrachlorosilane; potassium carbonate; copper(II) sulfate; In ethanol; 2: Ullmann condensation;

DOI:10.1039/b105422h

Reference yield: 84.0%

dichloromethane (75-09-2) + silver nitrate + 2,4,6-tris[p-(2,2'-dipyridylamino)phenyl]-benzene (391594-50-6) → [Ag(NO3)]3(1,3,5-tris(4-(2,2'-dipyridylamino)-phenyl)benzene)*1.5CH2Cl2

Guidance literature:

In methanol; dichloromethane; benzene; benzene, MeOH and a sonicated soln. of AgNO3 in MeOH successively layered upon soln. of C6H3(C6H4N(C5H4N)2)3 in CH2Cl2, vial covered in Al foil,stored for several days; elem. anal.;

DOI:10.1002/anie.200353126

upstream raw materials:

di(pyridin-2-yl)amine

1,3,5-tris(4-bromophenyl)benzene

para-bromoacetophenone

Refernces

• 1、 Pang, Jun,Marcotte, Eric J.-P.,Seward, Corey,Brown, R. Stephen,Wang, Suning. "A blue luminescent star-shaped Znii complex that can detect benzene". . p. 4042 - 4045. Retrieved 2007/10/03.