Bis(3-methoxyphenyl)methanone

Base Information

• Chemical Name: Bis(3-methoxyphenyl)methanone
• CAS No.: 39193-85-6
• Molecular Formula: C15H14O3
• Molecular Weight: 242.274
• Hs Code.: 2914509090
• DSSTox Substance ID: DTXSID00502175
• Nikkaji Number: J554.776H
• Wikidata: Q82355002
• Mol file: 39193-85-6.mol

Synonyms:3,3'-DIMETHOXYBENZOPHENONE;bis(3-methoxyphenyl)methanone;39193-85-6;MFCD01311539;m-methoxyphenyl ketone;Bis-(3-methoxyphenyl)methanone;SCHEMBL4823687;DTXSID00502175;CRMSZGRTWXOBKL-UHFFFAOYSA-N;AKOS010016106;CCG-325854;CS-0265568;EN300-99297;Z513732558

Chemical Property of Bis(3-methoxyphenyl)methanone

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Boiling Point: 395.459oC at 760 mmHg
• Flash Point: 184.535oC
• PSA: 35.53000
• Density: 1.124g/cm3
• LogP: 2.93480
• XLogP3: 3.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 4
• Exact Mass: 242.094294304
• Heavy Atom Count: 18
• Complexity: 251

Purity/Quality:

95% ^*data from raw suppliers

3,3'-Dimethoxybenzophenone 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=CC=CC(=C1)C(=O)C2=CC(=CC=C2)OC

Technology Process of Bis(3-methoxyphenyl)methanone

There total 26 articles about Bis(3-methoxyphenyl)methanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

3-methoxyphenyl bromide (2398-37-0) + chloroformic acid ethyl ester (541-41-3) → 3,3'-dimethoxybenzophenone (39193-85-6)

Guidance literature:

chloroformic acid ethyl ester; With cobalt 2,2'-bipyridine dibromide; 3-chloroprop-1-ene; trifluoroacetic acid; zinc; In acetonitrile; at 20 ℃; for 0.333333h;

3-methoxyphenyl bromide; In acetonitrile; at 20 ℃; for 4h;

DOI:10.1002/ejoc.201600738

Reference yield: 90.0%

bis(3-methoxyphenyl)methanol (55360-45-7) → 3,3'-dimethoxybenzophenone (39193-85-6)

Guidance literature:

With pyridinium chlorochromate; In dichloromethane;

DOI:10.1016/S0040-4039(00)95436-4

Reference yield: 90.0%

carbon monoxide (201230-82-2) + potassium 3-methoxyphenyltrifluoroborate → 3,3'-dimethoxybenzophenone (39193-85-6)

Guidance literature:

With iodine; palladium diacetate; sodium carbonate; at 80 ℃; for 15h; under 760.051 Torr;

DOI:10.1002/ejoc.201600689

upstream raw materials:

4-Methoxy-2-(3-methoxybenzoyl)benzoic acid

3,3'-dihydroxybenzophenone

dimethyl sulfate

bis-1,1-(3-methoxyphenyl)ethene

Downstream raw materials:

bis(3-methoxyphenyl)<(trimethylsily)oxy>acetonitrile

3,3-Bis-(3-methoxy-phenyl)-acrylonitrile

2-(4,6-Dimethoxy-pyrimidin-2-yloxy)-3-methoxy-3,3-bis-(3-methoxy-phenyl)-propionic acid methyl ester