Stannane, chloromethyldiphenyl-

Base Information

• Chemical Name: Stannane, chloromethyldiphenyl-
• CAS No.: 4167-84-4
• Molecular Formula: C13H13ClSn
• Molecular Weight: 323.409
• Mol file: 4167-84-4.mol

Synonyms:

Chemical Property of Stannane, chloromethyldiphenyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Stannane, chloromethyldiphenyl-

There total 19 articles about Stannane, chloromethyldiphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

triphenyl methyl tin (1089-59-4) → diphenyl methyl tin chloride (4167-84-4)

Guidance literature:

With hydrogenchloride; In methanol; benzene; Ph3CH3Sn dissolved in benzene/methanol 1/10, methanolic HCl added dropwise, allowed to stand for 48 h; solvents evapd., recrystd. twice with petroleum ether at 0°C, elem. anal.;

Reference yield: 70.0%

Tetramethylblei-(IV) (75-74-1) + diphenyltin(IV) dichloride (1135-99-5) → diphenyl methyl tin chloride (4167-84-4)

Guidance literature:

In chloroform-d1; at 20 ℃; for 2h; Sealed tube; Inert atmosphere;

DOI:10.1039/c7dt04520d

Reference yield: 60.0%

methyltin(IV) trichloride (993-16-8) + Tetraphenyllead (595-89-1) → diphenyl methyl tin chloride (4167-84-4)

Guidance literature:

In chloroform-d1; at 100 ℃; for 3h; Sealed tube; Inert atmosphere;

DOI:10.1039/c7dt04520d

upstream raw materials:

dimethyldiphenyltin

triphenyl methyl tin

tetramethylstannane

benzoyl chloride

Downstream raw materials:

HSnMePh₂

2-[methyldiphenylstannylpropyl]-2-methyl-1,3-dioxalane

(t-Bu)C₆H₂(O)OSnPh₂Me

diphenylmethylstannyltetracarbonyl(triphenylphosphine)manganese

Refernces

• 1、 Arias-Ugarte, Renzo N.,Pannell, Keith H.. "A utility for organoleads: Selective alkyl and aryl group transfer to tin". . p. 1703 - 1708. Retrieved 2018/02/09.
• 2、 Smith, Stuart E.,Sasaki, Jennifer M.,Bergman, Robert G.,Mondloch, Joseph E.,Finke, Richard G.. "Platinum-catalyzed phenyl and methyl group transfer from tin to iridium: Evidence for an autocatalytic reaction pathway with an unusual preference for methyl transfer". . p. 1839 - 1841. Retrieved 2008/09/17.