methyl(triphenyl)stannane

Base Information

• Chemical Name: methyl(triphenyl)stannane
• CAS No.: 1089-59-4
• Molecular Formula: C19H18 Sn
• Molecular Weight: 365.062
• Mol file: 1089-59-4.mol

Synonyms:Tin,methyltriphenyl- (7CI); Methyltriphenylstannane; Methyltriphenyltin; NSC 179744

Chemical Property of methyl(triphenyl)stannane

Chemical Property:

• Vapor Pressure: 4.03E-06mmHg at 25°C
• Boiling Point: 396°C at 760 mmHg
• Flash Point: 197.1°C

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of methyl(triphenyl)stannane

There total 45 articles about methyl(triphenyl)stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

triphenyltin chloride (639-58-7) + methyl iodide (74-88-4) → triphenyl methyl tin (1089-59-4)

Guidance literature:

triphenyltin chloride; With naphthalene; lithium; In tetrahydrofuran; at 20 ℃; for 3h; Inert atmosphere;

methyl iodide; In tetrahydrofuran; at 20 ℃; for 1h; Inert atmosphere; Schlenk technique;

DOI:10.1021/jacs.5b06587

Reference yield: 99.0%

triphenylstannane (892-20-6) + methyl iodide (74-88-4) → triphenyl methyl tin (1089-59-4)

Guidance literature:

With butyllithium; diisopropylamine; In tetrahydrofuran; hexane; soln. of BuLi in hexane added to soln. of (iPr)2NH in THF at 0°C,stirred for 20 min, cooled to -78°C, soln. of Ph3SnH in THF adde d, stirred for 1 h, warmed to -10°C, CH3I added, heated at 45°C for 1 h; cooled to ambient temp., aq. NH4Cl added, extracted with diethyl ether, combined org. phases dried over MgSO4, filtered, concd. under vac.; elem. anal.;

DOI:10.1039/b200317c

Reference yield: 93.0%

triphenyltin chloride (639-58-7) → triphenyl methyl tin (1089-59-4)

Guidance literature:

With CH₃MgI; In not given; stirring (3 h) at room temp.;;

upstream raw materials:

triphenylstannane

methyllithium

methyl iodide

triphenyltin chloride

Downstream raw materials:

trimethyltin(IV)chloride

diphenyl methyl tin chloride

methylphenyltin(IV) dichloride

trimethyl(phenyl)stannane

Refernces

• 1、 Des Tombe et al.. "-". . p. P9. Retrieved 1968.
• 2、 -. "METHOD FOR PRODUCING 14 GROUP METAL LITHIUM COMPOUND". . . Retrieved 2016/10/31.
• 3、 Wang, Dong-Yu,Wang, Chao,Uchiyama, Masanobu. "Stannyl-Lithium: A Facile and Efficient Synthesis Facilitating Further Applications". supporting information. p. 10488 - 10491. Retrieved 2015/09/28.