Thiocyanic acid, cyclohexyl ester

Base Information

• Chemical Name: Thiocyanic acid, cyclohexyl ester
• CAS No.: 4251-13-2
• Molecular Formula: C7H11NS
• Molecular Weight: 141.237
• Hs Code.: 2930909090
• Mol file: 4251-13-2.mol

Synonyms:Hexan-1-thiol, Tetrahexyl-tetrathioorthostannat;

Chemical Property of Thiocyanic acid, cyclohexyl ester

Chemical Property:

• Boiling Point: 111-112 °C(Press: 16 Torr)
• PSA: 49.09000
• Density: 1.0402 g/cm3(Temp: 25 °C)
• LogP: 2.53338

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Thiocyanic acid, cyclohexyl ester

There total 26 articles about Thiocyanic acid, cyclohexyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

ammonium thiocyanate + cyclohexanol (108-93-0) → thiocyanatocyclohexane (4251-13-2)

Guidance literature:

ammonium thiocyanate; With 1-chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octanebis(tetrafluoroborate); In acetonitrile; at 20 ℃; for 0.333333h;

cyclohexanol; In acetonitrile; for 1.25h;

DOI:10.1016/j.jfluchem.2012.03.005

Reference yield: 99.0%

potassium cyanide (151-50-8) + S-cyclohexyl 4-methylbenzenesulfonothioate (37556-51-7) → thiocyanatocyclohexane (4251-13-2) + potassium 4-methylbenzenesulfinate (19294-29-2)

Guidance literature:

at 40 ℃; for 53h;

DOI:10.1080/00397919908085956

Reference yield: 91.0%

cyclohexyl tosylate (953-91-3) + ammonium thiocyanate (1147550-11-5) → thiocyanatocyclohexane (4251-13-2)

Guidance literature:

ammonium thiocyanate; With montmorillonite K₁₀ clay; In acetone; at 20 ℃; for 0.666667h;

cyclohexyl tosylate; at 20 ℃; for 0.133333h; Neat (no solvent); Grinding;

DOI:10.1016/j.tetlet.2012.01.113

upstream raw materials:

1-bromocyclohexane

potassium thioacyanate

ammonium thiocyanate

cyclohexane

Downstream raw materials:

thiophosphoric S-cyclohexyl ester O,O'-diethyl ester

cyclohexyl(trifluoromethyl)sulfane

trimethylsilyl cyanide

S-Cyclohexyl-S-ethyl-dithiokohlensaeureimid