Methoxymethoxycyclohexane

Base Information

Chemical Name:Methoxymethoxycyclohexane
CAS No.:42604-09-1
Molecular Formula:C8H16O2
Molecular Weight:144.214
Hs Code.:
DSSTox Substance ID:DTXSID90452019
Nikkaji Number:J624.572B
Wikidata:Q82272365
Mol file:42604-09-1.mol

Synonyms:Methoxymethoxycyclohexane;methoxymethyloxy-cyclohexane;42604-09-1;(methoxymethoxy)cyclohexane;SCHEMBL2739873;DTXSID90452019;AKOS015906785

Suppliers and Price of Methoxymethoxycyclohexane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 0 raw suppliers

Chemical Property of Methoxymethoxycyclohexane

Chemical Property:

XLogP3:1.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:144.115029749
Heavy Atom Count:10
Complexity:77.3

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COCOC1CCCCC1

Technology Process of Methoxymethoxycyclohexane

There total 10 articles about Methoxymethoxycyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 109-72-8,29786-93-4
n-butyllithium

: 89727-03-7
O-(methoxymethyl)-1-(tri-n-butylstannyl)cyclohexanol

: 42604-09-1
(methoxymethoxy)cyclohexane

: 1461-25-2
tetra-n-butyltin(IV)

Guidance literature:: With methanol; In tetrahydrofuran; under argon; tin-compound in THF cooled to -78 °C; LiBu was added over 10 s; colorless solution after additional 10 s; after 2 min solution was quenched with MeOH;; poured into NH4Cl-soln. and petroleum ether, shaked 1 min, organic layer separated, washed (brine), dried (Na2SO4), filtered, concentrated (vacuo); chromatography (silica gel; ethyl acetate/petroleum ether 0.5:99.5); (1)H- and (13)C-NMR;;
DOI:10.1021/ja00211a024

Reference yield: 95.0%

: 89727-03-7
O-(methoxymethyl)-1-(tri-n-butylstannyl)cyclohexanol

: 42604-09-1
(methoxymethoxy)cyclohexane

Guidance literature:: With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 0.0333333h;
DOI:10.1021/ja00211a024

Reference yield: 94.0%

: 109-87-5
Dimethoxymethane

: 108-93-0
cyclohexanol

: 42604-09-1
(methoxymethoxy)cyclohexane

Guidance literature:: With zirconyl triflate; at 20 ℃; for 0.0833333h; chemoselective reaction; neat (no solvent);
DOI:10.1007/s00706-010-0310-8