1,7,7-trimethylbicyclo[2.2.1]heptan-2-amine

Base Information

• Chemical Name: 1,7,7-trimethylbicyclo[2.2.1]heptan-2-amine
• CAS No.: 4481-88-3
• Molecular Formula: C10H19N
• Molecular Weight: 153.268
• Hs Code.: 2921300090
• Mol file: 4481-88-3.mol

Synonyms:L-isoborneol;methylisobornyl ether;isoborneol methyl ether;isobornyl alcohol;Isobornylamin;2-bornylamine;isobornyl amine;

Chemical Property of 1,7,7-trimethylbicyclo[2.2.1]heptan-2-amine

Chemical Property:

• PSA: 26.02000
• LogP: 2.86020

Purity/Quality:

97% ^*data from raw suppliers

1,7,7-TRIMETHYLBICYCLO[2.2.1]HEPTAN-2-AMINE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,7,7-trimethylbicyclo[2.2.1]heptan-2-amine

There total 8 articles about 1,7,7-trimethylbicyclo[2.2.1]heptan-2-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 33.0%

(1S,4S)-N-benzyl-1,7,7-trimethylbicycto[2,2.1]heptan-2-amine → (1S,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-amine (464-42-6,2223-67-8,4481-88-3,32511-34-5,32511-35-6,37606-04-5,94319-59-2,122038-71-5,128574-40-3)

Guidance literature:

With palladium 10% on activated carbon; hydrogen; In methanol; at 20 ℃; for 4h; under 775.743 Torr;

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + d-camphor N-nitroimine (114717-12-3) → (R,R)-camphor oxime (2792-42-9) + bornylamine (4481-88-3) + dl-camphene (565-00-4)

Guidance literature:

isomer(ic) I;

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + camphene (5794-04-7) + water (7732-18-5) → camphene hydrate (13429-40-8,13429-57-7,52437-40-8,64397-62-2,64474-11-9,91547-95-4,465-31-6,28974-22-3) + bornylamine (4481-88-3) + dl-camphene (565-00-4) + 1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol (507-70-0)

Guidance literature:

anschl. mit wss. KOH bei 160grad;

upstream raw materials:

hydrogenchloride

camphene

water

d-camphor N-nitroimine

Downstream raw materials:

camphene

2-endo-benzoylamino, bornane

butyrylbornylamine

{2-[2-(2-Methoxy-phenoxy)-ethoxy]-ethyl}-(1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl)-amine