Camphene

Base Information

• Chemical Name: Camphene
• CAS No.: 79-92-5
• Deprecated CAS: 565-00-4
• Molecular Formula: C10H16
• Molecular Weight: 136.237
• Hs Code.: 2902.19 Oral rat LD50: 5000 mg/kg
• European Community (EC) Number: 201-234-8
• ICSC Number: 1704
• NSC Number: 4165
• UN Number: 2319,1325
• UNII: G3VG94Z26E
• DSSTox Substance ID: DTXSID8026488
• Nikkaji Number: J39.020H
• Wikipedia: Camphene
• Wikidata: Q416775
• Metabolomics Workbench ID: 127644
• ChEMBL ID: CHEMBL2268550
• Mol file: 79-92-5.mol

Synonyms:camphene

Chemical Property of Camphene

Chemical Property:

• Appearance/Colour: colorless to white crystalline solid
• Vapor Pressure: 3.38mmHg at 25°C
• Melting Point: 51-52 °C
• Refractive Index: 1.4500 - 1.4550
• Boiling Point: 158.6 °C at 760 mmHg
• Flash Point: 34.9 °C
• PSA: 0.00000
• Density: 0.88 g/cm³
• LogP: 2.99870
• Storage Temp.: Flammables area
• Solubility.: 0.0042g/l
• Water Solubility.: practically insoluble
• XLogP3: 3.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 136.125200510
• Heavy Atom Count: 10
• Complexity: 177
• Transport DOT Label: Flammable Liquid

Purity/Quality:

99.9% ^*data from raw suppliers

DL-Camphene(containsupto20%tricyclene) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F
• Hazard Codes: F,N
• Statements: 11-10-50/53-36
• Safety Statements: 16-33-61-60-26

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Biological Agents -> Wood Dusts & Extracts
• Canonical SMILES: CC1(C2CCC(C2)C1=C)C
• Inhalation Risk: A nuisance-causing concentration of airborne particles can be reached quickly when dispersed, especially if powdered.
• Effects of Short Term Exposure: The substance is irritating to the eyes.
• Uses: Camphene is used in the preparation of fragrances and as a food additive for flavoring. Manufacture of synthetic camphor, camphor substitute.

Technology Process of Camphene

There total 134 articles about Camphene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

exo-2-nitroaminobornane (91087-37-5,124666-29-1) → 1,7,7-trimethyltricyclo[2.2.1.02,6]heptane (508-32-7) + camphene (79-92-5)

Guidance literature:

at 130 ℃; for 60h;

Reference yield: 20.0%

Pinene (80-56-8,177698-18-9,25766-18-1) → 1-methyl-4-isopropyl-1,3-cyclohexadiene (99-86-5) + 1,7,7-trimethyltricyclo[2.2.1.02,6]heptane (508-32-7) + camphene (79-92-5) + crithmene (99-85-4)

Guidance literature:

thionin-supported zeolite Na-Y; In hexane; at 20 ℃; for 0.5h; Product distribution;

DOI:10.1002/poc.557

Reference yield: 14.8%

isobornyl acetate (76-49-3,125-12-2,5655-61-8,6626-35-3,17283-45-3,20347-65-3,28974-17-6,36386-52-4,71424-71-0,92618-89-8) → ethene (74-85-1) + 1,7,7-trimethylbicyclo[2.2.1]hept-2-ene (464-17-5) + 1,7,7-trimethyltricyclo[2.2.1.02,6]heptane (508-32-7) + camphene (79-92-5) + 1,5,5-trimethyl-cyclopenta-1,3-diene (4249-09-6) + acetic acid (64-19-7,77671-22-8)

Guidance literature:

at 320 ℃; Kinetics; pyrolysis, other temperature;

upstream raw materials:

camphene hydrate

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

d-borneol

bornyl chloride

Downstream raw materials:

(+/-)-N-(2,3,3-trimethyl-[2exo]norbornyl)-formamide

bornyl chloride

endo-2,2-dimethyl-3-hydroxymethylbicyclo<2.2.1>heptane

10 bromocamphor

Refernces

Synthesis and biological screening of 4-(3,3-dimethylspiro{bicyclo[2.2.1] heptan-2,5′-isoxazoline-2}- 3′-yl)-2-aryl-2,3-dihydro-1H-1,5- benzodiazepines

10.1002/jhet.194

The research involves the synthesis of a series of novel hybrid molecules that combine isoxazoles and benzodiazepines, with a dimethyl bicycloheptyl group added to enhance lipophilicity. The aim was to create compounds that could potentially act on multiple biological targets or enhance each other's activity. Key chemicals used in the synthesis include camphene, acetone, iron (III) nitrate nonahydrate, various aromatic aldehydes, and o-phenylenediamine. The synthesized compounds were characterized using techniques like NMR and IR spectroscopy. The compounds were then screened for their antibacterial and antifungal activities against a range of microbial strains, but none showed promising antimicrobial or antifungal activity up to concentrations of 180 μg/mL.