Ethyldimethylsilane

Base Information

• Chemical Name: Ethyldimethylsilane
• CAS No.: 758-21-4
• Molecular Formula: C4H12Si
• Molecular Weight: 88.2248
• European Community (EC) Number: 212-061-2
• DSSTox Substance ID: DTXSID90883561
• Mol file: 758-21-4.mol

Synonyms:Ethyldimethylsilane;758-21-4;Silane, ethyldimethyl-;EINECS 212-061-2;Dimethylethylsilane, 98%;DTXSID90883561;MFCD00009016;AKOS015915495

Chemical Property of Ethyldimethylsilane

Chemical Property:

• Vapor Pressure: 6.05 psi ( 20 °C)
• Refractive Index: n20/D 1.378(lit.)
• Boiling Point: 45 °C at 760 mmHg
• Flash Point: <−30 °F
• PSA: 0.00000
• Density: 0.668 g/mL at 25 °C(lit.)
• LogP: 1.49300
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 87.063001885
• Heavy Atom Count: 5
• Complexity: 17.6

Purity/Quality:

98%,99%, ^*data from raw suppliers

Dimethylethylsilane 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi；F
• Hazard Codes: F,Xi
• Statements: 11-36/37/38
• Safety Statements: 16-26-33-36-7/9

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC[Si](C)C
• Uses: Dimethylethylsilane can be used as:A reducing agent in the ligand-free carbon-sulfur bond cleavage reaction.A promoter in cycloisomerization of 1,6-dienes using palladium catalyst.

Technology Process of Ethyldimethylsilane

There total 9 articles about Ethyldimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-methyl-propan-1-ol (78-83-1) + [3H3]ethylsilylium ion (280757-21-3) → dimethylethylsilane (758-21-4) + 1,1,3,3-Tetramethyldisiloxane (3277-26-7) + C4H9(3)HO + dimethylbutoxysilane

Guidance literature:

at 20 ℃; for 2922h; Product distribution;

Reference yield:

dimethylmonochlorosilane (1066-35-9) + diethylzinc (557-20-0) → dimethylethylsilane (758-21-4)

Guidance literature:

With 1-methyl-1H-imidazole; In benzene-d6; at 20 ℃;

Reference yield:

dimethylmonochlorosilane (1066-35-9) → dimethylethylsilane (758-21-4)

Guidance literature:

In tetrahydrofuran;

DOI:10.1021/ja01469a033

upstream raw materials:

diethylmethylsilane

ethyldimethylsilyl chloride

ethyldichlorosilane

methylmagnesium chloride

Downstream raw materials:

ethyl-dimethyl-phenethyl-silane

p-benzylanizole

C₄H₁₁Si⁽¹⁺⁾

1,2-diethyl-1,1,2,2-tetramethyldisilane

Refernces

• 1、 -. "PROCESS FOR FUNCTIONALIZATION OF ORGANO-ZINC COMPOUNDS WITH HALOSILANES USING BASIC NITROGEN CONTAINING HETEROCYCLES AND SILYL-FUNCTIONALIZED COMPOUNDS PREPARED THEREBY". Paragraph 0033. . Retrieved 2019/10/15.
• 2、 Nefedov, O. M.,Skell, Philip S.. "FORMATION AND REACTIONS OF DIMETHYLSILYLENE AND DIMETHYLGERMYLENE". . p. 320 - 322. Retrieved 2007/10/02.