Dicyclohexyl peroxide

Base Information

• Chemical Name: Dicyclohexyl peroxide
• CAS No.: 1758-61-8
• Molecular Formula: C12H22O2
• Molecular Weight: 198.305
• Hs Code.: 2909600000
• European Community (EC) Number: 217-155-7
• UNII: K2S7BLU3WA
• DSSTox Substance ID: DTXSID00170030
• Nikkaji Number: J203.165E
• Wikidata: Q83039878
• Mol file: 1758-61-8.mol

Synonyms:Dicyclohexyl peroxide;1758-61-8;cyclohexylperoxycyclohexane;EINECS 217-155-7;Peroxide, dicyclohexyl;K2S7BLU3WA;SCHEMBL36848;DTXSID00170030

Chemical Property of Dicyclohexyl peroxide

Chemical Property:

• Vapor Pressure: 0.0227mmHg at 25°C
• Boiling Point: 258°C at 760 mmHg
• Flash Point: 86.9°C
• PSA: 18.46000
• Density: 0.97g/cm³
• LogP: 3.60000
• XLogP3: 3.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 198.161979940
• Heavy Atom Count: 14
• Complexity: 128

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CCC(CC1)OOC2CCCCC2

Technology Process of Dicyclohexyl peroxide

There total 2 articles about Dicyclohexyl peroxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

cyclohexyl mesylate (16156-56-2) → dicyclohexyl peroxide (1758-61-8) + cyclohexene (110-83-8) + cyclohexanol (108-93-0)

Guidance literature:

With tetrahexylammonium chloride; In hexane; at 25 ℃; for 2h; Product distribution; other cycloalkyl methanesulfonate esters;

Reference yield:

dicyclohexyl peroxydicarbonate (1561-49-5) → cyclohexylcyclohexane (92-51-3) + cyclohexanone (108-94-1,11119-77-0,9003-41-2,9075-99-4) + dicyclohexyl peroxide (1758-61-8) + cyclohexanol (108-93-0)

Guidance literature:

In cyclohexane; at 80 ℃; for 1h; Product distribution; Mechanism; other cyclohexyloxy radical sources, var. temperature; the effect of the number of atoms separating potential CyO radicals, the effect of O₂;

DOI:10.1021/jo00350a078

upstream raw materials:

dicyclohexyl peroxydicarbonate

cyclohexyl mesylate

Refernces

• 1、 Druliner, J. D.. "PREPARATION OF DICYCLOALKYL PEROXIDES INCLUDING DICYCLOHEXYL PEROXIDE". . p. 115 - 120. Retrieved 2007/10/02.