S-(4-chlorophenyl) benzenecarbothioate

Base Information

• Chemical Name: S-(4-chlorophenyl) benzenecarbothioate
• CAS No.: 4906-35-8
• Molecular Formula: C13H9ClOS
• Molecular Weight: 248.733
• Mol file: 4906-35-8.mol

Synonyms:S-4-chlorophenyl benzothioate;S-(4-chlorophenyl) benzenecarbothioate;S-p-chlorophenyl benzothioate;S-4-chlorophenyl thiobenzoate;S-(p-chlorophenyl) benzothioathe;S-(p-chlorophenyl) benzenecarbothioate;

Chemical Property of S-(4-chlorophenyl) benzenecarbothioate

Chemical Property:

• PSA: 42.37000
• LogP: 4.27250

Purity/Quality:

95% ^*data from raw suppliers

S-(4-CHLOROPHENYL)BENZENECARBOTHIOATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of S-(4-chlorophenyl) benzenecarbothioate

There total 40 articles about S-(4-chlorophenyl) benzenecarbothioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

tert-butyl benzoyl(tert-butoxycarbonyl)carbamate (135364-97-5) + p-Chlorothiophenol (106-54-7) → S-(4-chlorophenyl) benzothioate (4906-35-8)

Guidance literature:

With sodium carbonate; In 1,4-dioxane; at 80 ℃; for 18h; Inert atmosphere;

DOI:10.1177/1747519819873514

Reference yield: 93.0%

4,4'-dichlorodiphenyl disulfide (1142-19-4) + benzoic acid anhydride (93-97-0) → S-(4-chlorophenyl) benzothioate (4906-35-8)

Guidance literature:

With Cp₂Ti(OSO₂C₈F₁₇)2*2H₂O*THF; zinc; In tetrahydrofuran; at 20 ℃; for 1h;

DOI:10.1080/00397910903419803

Reference yield: 93.0%

4,4'-dichlorodiphenyl disulfide (1142-19-4) + benzaldehyde (100-52-7) → S-(4-chlorophenyl) benzothioate (4906-35-8)

Guidance literature:

With di-tert-butyl peroxide; In neat (no solvent); at 120 ℃; for 12h; Inert atmosphere; Schlenk technique;

DOI:10.1039/c4gc00025k

upstream raw materials:

benzoyl chloride

p-Chlorothiophenol

dimethyl benzoylphosphonate

benzoic acid

Downstream raw materials:

4-chloro-benzenesulfonic acid

benzoic acid

Dithiobenzoic acid 4-chloro-phenyl ester

4,4'-dichlorodiphenyl disulfide

Refernces

• 1、 -. "Method for synthesizing thioester through cross-coupling of visible light-catalyzed sodium sulfinate and acyl chloride". Paragraph 0028-0031. . Retrieved 2021/09/11.
• 2、 Wang, Lingxiao,Qiao, Jie,Wei, Jiancong,Liang, Zhiwu,Xu, Xinhua,Li, Ningbo. "Air-stable binuclear Titanium(IV) salophen perfluorobutanesulfonate with zinc power catalytic system and its application to C–S and C–Se bond formation". . . Retrieved 2020/01/08.