Benzoic acid, 4-methoxy-, (1R)-3-azido-1-[[(4R,6R)-6-[[(4S,6S)-6-[(2S)-4-(2,2-dimethyl-1-oxoprop oxy)-2-[(4-methoxybenzoyl)oxy]butyl]-2,2-dimethyl-1,3-dioxan-4-yl]methyl ]-2,2-dimethyl-1,3-dioxan-4-yl]methyl]propyl ester

Base Information

Chemical Name:Benzoic acid, 4-methoxy-, (1R)-3-azido-1-[[(4R,6R)-6-[[(4S,6S)-6-[(2S)-4-(2,2-dimethyl-1-oxoprop oxy)-2-[(4-methoxybenzoyl)oxy]butyl]-2,2-dimethyl-1,3-dioxan-4-yl]methyl ]-2,2-dimethyl-1,3-dioxan-4-yl]methyl]propyl ester
CAS No.:499778-93-7
Molecular Formula:C42H59N3O12
Molecular Weight:797.943
Hs Code.:

Benzoic acid, 4-methoxy-,
(1R)-3-azido-1-[[(4R,6R)-6-[[(4S,6S)-6-[(2S)-4-(2,2-dimethyl-1-oxoprop
oxy)-2-[(4-methoxybenzoyl)oxy]butyl]-2,2-dimethyl-1,3-dioxan-4-yl]methyl
]-2,2-dimethyl-1,3-dioxan-4-yl]methyl]propyl ester

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Chemical Property of Benzoic acid, 4-methoxy-, (1R)-3-azido-1-[[(4R,6R)-6-[[(4S,6S)-6-[(2S)-4-(2,2-dimethyl-1-oxoprop oxy)-2-[(4-methoxybenzoyl)oxy]butyl]-2,2-dimethyl-1,3-dioxan-4-yl]methyl ]-2,2-dimethyl-1,3-dioxan-4-yl]methyl]propyl ester

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Technology Process of Benzoic acid, 4-methoxy-, (1R)-3-azido-1-[[(4R,6R)-6-[[(4S,6S)-6-[(2S)-4-(2,2-dimethyl-1-oxoprop oxy)-2-[(4-methoxybenzoyl)oxy]butyl]-2,2-dimethyl-1,3-dioxan-4-yl]methyl ]-2,2-dimethyl-1,3-dioxan-4-yl]methyl]propyl ester

There total 8 articles about Benzoic acid, 4-methoxy-, (1R)-3-azido-1-[[(4R,6R)-6-[[(4S,6S)-6-[(2S)-4-(2,2-dimethyl-1-oxoprop oxy)-2-[(4-methoxybenzoyl)oxy]butyl]-2,2-dimethyl-1,3-dioxan-4-yl]methyl ]-2,2-dimethyl-1,3-dioxan-4-yl]methyl]propyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₄₃H₆₂O₁₅S

: 499778-93-7
(1R)-3-azido-1-{[(4R,6S)-6-{[(4R,6S)-6-{(2S)-4-(2,2-dimethyl-1-oxopropoxy)-2-[(4-methoxybenzoyl)oxy]butyl}-2,2-dimethyl-1,3-dioxan-4-yl]methyl}-2,2-dimethyl-1,3-dioxan-4-yl]methyl}propyl 4-methoxybenzoate

Guidance literature:: With sodium azide; In N,N-dimethyl-formamide; at 60 ℃; for 5h;
DOI:10.1055/s-2002-34381

Reference yield:

: 3282-30-2
pivaloyl chloride

: 499778-93-7
(1R)-3-azido-1-{[(4R,6S)-6-{[(4R,6S)-6-{(2S)-4-(2,2-dimethyl-1-oxopropoxy)-2-[(4-methoxybenzoyl)oxy]butyl}-2,2-dimethyl-1,3-dioxan-4-yl]methyl}-2,2-dimethyl-1,3-dioxan-4-yl]methyl}propyl 4-methoxybenzoate

Guidance literature:: Multi-step reaction with 7 steps

1: 75 percent / pyridine / CH₂Cl₂ / 12 h / 0 °C

2: aq. NMO / OsO₄ / acetone; CCl₄ / 11 h / 20 °C

3: aq. NaIO₄ / dioxane / 12 h / 20 °C

4: (Me₄N)BH(OAc)3 / acetic acid / 2 h / 20 °C

5: 127 mg / pyridinium toluene-4-sulfonate / acetone / 2 h / 0 °C

6: Et₃N / CH₂Cl₂ / 1 h / 0 °C

7: 65 mg / NaN₃ / dimethylformamide / 5 h / 60 °C

With pyridine; sodium periodate; sodium azide; N-methyl-2-indolinone; pyridinium p-toluenesulfonate; triethylamine; tetramethylammonium triacetoxyborohydride; osmium(VIII) oxide; In 1,4-dioxane; tetrachloromethane; dichloromethane; acetic acid; N,N-dimethyl-formamide; acetone; 3: Malaprade cleavage;
DOI:10.1055/s-2002-34381

Reference yield:

: 321146-39-8
(1R,6R)-6-Hydroxy-4-{(4R,6S)-6-{(2S)-4-[(2,2-dmethyl-1-oxopropyl)oxy]-2-[(4-methoxybenzoyl)oxy]butyl}-2,2-dimethyl-1,3-dioxan-4-yl}methylcyclohept-3-en-1-yl 4-methoxybenzoate

: 499778-93-7
(1R)-3-azido-1-{[(4R,6S)-6-{[(4R,6S)-6-{(2S)-4-(2,2-dimethyl-1-oxopropoxy)-2-[(4-methoxybenzoyl)oxy]butyl}-2,2-dimethyl-1,3-dioxan-4-yl]methyl}-2,2-dimethyl-1,3-dioxan-4-yl]methyl}propyl 4-methoxybenzoate

Guidance literature:: Multi-step reaction with 6 steps

1: aq. NMO / OsO₄ / acetone; CCl₄ / 11 h / 20 °C

2: aq. NaIO₄ / dioxane / 12 h / 20 °C

3: (Me₄N)BH(OAc)3 / acetic acid / 2 h / 20 °C

4: 127 mg / pyridinium toluene-4-sulfonate / acetone / 2 h / 0 °C

5: Et₃N / CH₂Cl₂ / 1 h / 0 °C

6: 65 mg / NaN₃ / dimethylformamide / 5 h / 60 °C

With sodium periodate; sodium azide; N-methyl-2-indolinone; pyridinium p-toluenesulfonate; triethylamine; tetramethylammonium triacetoxyborohydride; osmium(VIII) oxide; In 1,4-dioxane; tetrachloromethane; dichloromethane; acetic acid; N,N-dimethyl-formamide; acetone; 2: Malaprade cleavage;
DOI:10.1055/s-2002-34381