Methyl 4-chloro-3-methoxy-2-butenoate

Base Information

Chemical Name:Methyl 4-chloro-3-methoxy-2-butenoate
CAS No.:85153-60-2
Molecular Formula:C₆H₉ClO₃
Molecular Weight:164.589
Hs Code.:
European Community (EC) Number:285-842-9
Nikkaji Number:J309.845A
Mol file:85153-60-2.mol

Synonyms:EINECS 285-842-9;Methyl 4-chloro-3-methoxy-2-butenoate;85153-60-2;methyl (Z)-4-chloro-3-methoxybut-2-enoate;SCHEMBL589407;JNYMRXDQVPIONI-HYXAFXHYSA-;JNYMRXDQVPIONI-HYXAFXHYSA-N;Methyl(E)-4-chloro-3-methoxy-2-butenoate;4-Chloro-3-methoxy-2-butenoic acid methyl ester;Methyl (2Z)-4-chloro-3-methoxy-2-butenoate #;J-800348;InChI=1/C6H9ClO3/c1-9-5(4-7)3-6(8)10-2/h3H,4H2,1-2H3/b5-3-

Suppliers and Price of Methyl 4-chloro-3-methoxy-2-butenoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
METHYL-4-CHLORO-3-METHOXY-2-(E)-BUTENOATE 97.00%
5MG
$ 497.93

Total 10 raw suppliers

Chemical Property of Methyl 4-chloro-3-methoxy-2-butenoate

Chemical Property:

Vapor Pressure:0.0643mmHg at 25°C
Melting Point:25 °C
Refractive Index:1.483-1.485
Boiling Point:230.9 °C at 760 mmHg
Flash Point:99 °C
PSA：35.53000
Density:1.157 g/cm³
LogP:0.92850
Water Solubility.:insoluble
XLogP3:0.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:4
Exact Mass:164.0240218
Heavy Atom Count:10
Complexity:142

Purity/Quality:

98% ^*data from raw suppliers

METHYL-4-CHLORO-3-METHOXY-2-(E)-BUTENOATE 97.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s): C
Hazard Codes:C
Statements: 22-34
Safety Statements: 26-36/37/39-45

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=CC(=O)OC)CCl
Isomeric SMILES:CO/C(=C\C(=O)OC)/CCl

Technology Process of Methyl 4-chloro-3-methoxy-2-butenoate

There total 5 articles about Methyl 4-chloro-3-methoxy-2-butenoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.4%

: 67-56-1
methanol

: 32807-28-6,935731-94-5
Methyl 4-chloroacetoacetate

: 110104-60-4,85153-60-2
(E)-4-chloro-3-methoxy-but-2-enoic acid methyl ester

Guidance literature:: methanol; Methyl 4-chloroacetoacetate; With thionyl chloride; at -10 - 20 ℃;

With methanesulfonic acid; at 150 ℃; under 75.006 Torr;
DOI:10.1016/S0040-4020(02)00178-3

Reference yield: 83.0%

: 67-56-1
methanol

: 32807-28-6,935731-94-5
Methyl 4-chloroacetoacetate

: 85153-60-2
C₆H₉ClO₃

Guidance literature:: methanol; Methyl 4-chloroacetoacetate; With thionyl chloride; at -10 - 20 ℃; for 3h;

With methanesulfonic acid; at 125 - 130 ℃; for 3h;
DOI:10.1021/acs.orglett.6b02924

Reference yield:

: 41295-64-1
4-chloroacetoacetyl chloride

: 110104-60-4,85153-60-2
(E)-4-chloro-3-methoxy-but-2-enoic acid methyl ester

Guidance literature:: With hydrogenchloride; sodium hydroxide; methanesulfonic acid; sodium chloride; In thionyl chloride; dichloromethane; toluene;