N-Allyl(trimethylsilyl)carbamate

Base Information

• Chemical Name: N-Allyl(trimethylsilyl)carbamate
• CAS No.: 51041-96-4
• Molecular Formula: C7H15NO2Si
• Molecular Weight: 173.287
• DSSTox Substance ID: DTXSID50498852
• Nikkaji Number: J845.055B
• Wikidata: Q82349172
• Mol file: 51041-96-4.mol

Synonyms:trimethylsilyl allylcarbamate;N-Allyl(trimethylsilyl)carbamate;51041-96-4;DTXSID50498852;VBKFGBSEJKXRCI-UHFFFAOYSA-N;Trimethylsilyl prop-2-en-1-ylcarbamate

Chemical Property of N-Allyl(trimethylsilyl)carbamate

Chemical Property:

• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 173.087205256
• Heavy Atom Count: 11
• Complexity: 151

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(C)OC(=O)NCC=C

Technology Process of N-Allyl(trimethylsilyl)carbamate

There total 2 articles about N-Allyl(trimethylsilyl)carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

carbon dioxide (124-38-9,18923-20-1) + 1,1,1,3,3,3-hexamethyl-disilazane (999-97-3) → N,O-bis<(trimethylsilyl)oxy>acetamide (35342-88-2) + trimethylsilyl allylcarbamate (51041-96-4)

Guidance literature:

With (chloromethyl)methoxydimethylsilane; 1-amino-2-propene; at 45 - 47 ℃; for 10h;

DOI:10.1007/BF00703492

Reference yield: 12.0%

carbon dioxide (124-38-9,18923-20-1) + 1-amino-2-propene (107-11-9,30551-89-4) + 1,1,1,3,3,3-hexamethyl-disilazane (999-97-3) → N,O-bis<(trimethylsilyl)oxy>acetamide (35342-88-2) + trimethylsilyl allylcarbamate (51041-96-4)

Guidance literature:

With (chloromethyl)methoxydimethylsilane; at 45 - 47 ℃; for 10h;

DOI:10.1007/BF00703492

Reference yield: 55.0%

trimethylsilyl allylcarbamate (51041-96-4) → 1,3-diallylurea (1801-72-5)

Guidance literature:

at 150 - 160 ℃; for 3h;

DOI:10.1134/S1070363206030182

upstream raw materials:

carbon dioxide

1-amino-2-propene

1,1,1,3,3,3-hexamethyl-disilazane

Downstream raw materials:

allylisocyanate

1,3-diallylurea