meso-Tetra-3'-pyridylporphyrin

Base Information

• Chemical Name: meso-Tetra-3'-pyridylporphyrin
• CAS No.: 40882-83-5
• Molecular Formula: C40H26N8
• Molecular Weight: 618.7
• Mol file: 40882-83-5.mol

Synonyms:5,10,15,20-tetra(pyrid-3-yl)porphine;5,10,15,20-tetra-(3-pyridyl) porphine;5,10,15,20-tetrakis(3-pyridyl)porphyrin;5,10,15,20-tetrakis(m-pyridyl)porphyrin;5,10,15,20-tetra(3-pyridyl)porphyrin;TETRA(PYRIDIN-3-YL)PORPHYRIN;

Chemical Property of meso-Tetra-3'-pyridylporphyrin

Chemical Property:

• PSA: 97.00000
• Density: 1.335g/cm³
• LogP: 4.98730

Purity/Quality:

98%,99%, ^*data from raw suppliers

Meso-Tetra(3-pyridyl)porphine 97+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of meso-Tetra-3'-pyridylporphyrin

There total 8 articles about meso-Tetra-3'-pyridylporphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 28.0%

1-nicotinoyl-5-(3-pyridyl)dipyrromethane (1046493-90-6) + 5-formyl-2,2'-dipyrrylmethane (36746-27-7) → 5,10,15,20-tetra(3-pyridyl)porphyrin (40882-83-5) + 5,10-di(3-pyridyl)porphyrin + porphyrin (101-60-0)

Guidance literature:

With air; 1,8-diazabicyclo[5.4.0]undec-7-ene; magnesium bromide; In toluene; at 115 ℃; microwave irradiation;

DOI:10.1021/jo800588n

Reference yield: 15.0%

3-pyridinecarboxaldehyde (500-22-1) + pyrrole (109-97-7,30604-81-0) + 2,5-bis[hydroxy(phenyl)methyl]furan (171824-88-7) → 5,10,15,20-tetra(3-pyridyl)porphyrin (40882-83-5) + 5,10,15,20-tetraphenyl-21,23-dioxaporphyrine + 5,20-diphenyl-10,15-bis(3-pyridyl)-21-oxaporphyrin

Guidance literature:

In propionic acid; for 3h; Heating;

DOI:10.1016/S0040-4020(03)00183-2

Reference yield: 13.0%

3-pyridinecarboxaldehyde (500-22-1) + pyrrole (109-97-7,30604-81-0) + 2,5-bis(α-hydroxy-α-phenylmethyl)thiophene (57546-55-1) → 5,10,15,20-tetrakisphenyl-21,23-dithiaporphyrin (57511-57-6) + 5,10,15,20-tetra(3-pyridyl)porphyrin (40882-83-5) + 5,20-diphenyl-10,15-bis(3-pyridyl)-21-thiaporphyrin

Guidance literature:

In propionic acid; for 3h; Heating;

DOI:10.1016/S0040-4020(03)00183-2

upstream raw materials:

3-pyridinecarboxaldehyde

pyrrole

4-n-dodecyloxybenzaldehyde

2,5-bis(α-hydroxy-α-phenylmethyl)thiophene

Downstream raw materials:

dihydrogen meso-tetra(N-methyl-3-pyridyl)porphyrin tetrachloride