(4-Iodobut-3-en-2-yl)(trimethyl)silane

Base Information

Chemical Name:(4-Iodobut-3-en-2-yl)(trimethyl)silane
CAS No.:52685-51-5
Molecular Formula:C7H15ISi
Molecular Weight:254.186
Hs Code.:2931900090
DSSTox Substance ID:DTXSID70699369
Mol file:52685-51-5.mol

Synonyms:DTXSID70699369;(4-Iodobut-3-en-2-yl)(trimethyl)silane

Suppliers and Price of (4-Iodobut-3-en-2-yl)(trimethyl)silane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
((E)-3-IODO-1-METHYLPROPENYL)-TRIMETHYLSILANE 95.00%
5MG
$ 501.63

Total 1 raw suppliers

Chemical Property of (4-Iodobut-3-en-2-yl)(trimethyl)silane

Chemical Property:

Vapor Pressure:0.81mmHg at 25°C
Boiling Point:188.9oC at 760 mmHg
Flash Point:68oC
PSA：0.00000
Density:1.323g/cm3
LogP:3.66340
Solubility.:freely sol organic solvents.
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:2
Exact Mass:253.99877
Heavy Atom Count:9
Complexity:102

Purity/Quality:

98%Min ^*data from raw suppliers

((E)-3-IODO-1-METHYLPROPENYL)-TRIMETHYLSILANE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C=CI)[Si](C)(C)C
Physical properties bp 60 °C/20 mmHg.
Uses (E)-1-Iodo-3-trimethylsilyl-2-butene can be used as annulation reagent; alkylative equivalent of 3-buten-2-one; 3-ketobutyl synthon.

Technology Process of (4-Iodobut-3-en-2-yl)(trimethyl)silane

There total 5 articles about (4-Iodobut-3-en-2-yl)(trimethyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 52685-50-4
(2E)-3-(trimethylsilyl)crotyl alcohol

: 52685-51-5
(E)-(3-iodo-1-methyl-1-propenyl)-trimethylsilane

Guidance literature:: With N-iodo-succinimide; triphenylphosphine; In dichloromethane; at 0 - 20 ℃;
DOI:10.1021/jo0480803

Reference yield:

: 116399-78-1
((E)-3-chloro-1-methylpropenyl)trimethylsilane

: 52685-51-5
(E)-(3-iodo-1-methyl-1-propenyl)-trimethylsilane

Guidance literature:: With sodium iodide; In butanone; at 50 ℃; for 1h;
DOI:10.1055/s-1976-24200

Reference yield:

: 105575-91-5,97632-90-1
(Z)-⁽³⁾-(trimethylsilyl)-3-iodo-2-propen-1-ol

: 52685-51-5
(E)-(3-iodo-1-methyl-1-propenyl)-trimethylsilane

Guidance literature:: Multi-step reaction with 3 steps

2: CCl₄, Ph₃P

3: NaI / butan-2-one

With tetrachloromethane; triphenylphosphine; sodium iodide; In butanone;
DOI:10.1021/ja00818a071